360015
丙二酸叔丁基甲酯
95%
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关于此项目
线性分子式:
CH3OCOCH2COOC(CH3)3
化学文摘社编号:
分子量:
174.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
255-919-1
Beilstein/REAXYS Number:
1772136
MDL number:
Assay:
95%
Form:
liquid
产品名称
丙二酸叔丁基甲酯, 95%
InChI key
XPSYZCWYRWHVCC-UHFFFAOYSA-N
InChI
1S/C8H14O4/c1-8(2,3)12-7(10)5-6(9)11-4/h5H2,1-4H3
SMILES string
COC(=O)CC(=O)OC(C)(C)C
assay
95%
form
liquid
impurities
5% dimethyl malonate
refractive index
n20/D 1.415 (lit.)
bp
80 °C/11 mmHg (lit.)
density
1.03 g/mL at 25 °C (lit.)
functional group
ester
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General description
tert-Butyl methyl malonate is an ester. Stereospecific Pd(O)-catalyzed addition of tert-butyl methyl malonate to allylic carbonates is reported.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
174.2 °F - closed cup
flash_point_c
79 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Bingli Yan et al.
The Journal of organic chemistry, 69(8), 2859-2862 (2004-04-13)
A combination of cross-metathesis and malonate addition was applied to a formal synthesis of the mammalian lignan enterolactone 5. The cross-metathesis of alkene 6 and phosphonate 3a gave the substituted allylic phosphonate 3d. The palladium-catalyzed addition of malonate 10d to
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