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36037

氯-[2′-(二甲氨基)-2-联苯基]-(二去甲冰片基膦)-钯

≥99.0% (C)

别名:

Chloro-[2′-(dimethylamino)-2-biphenylyl]-(dinorbornylphosphine)-palladium, SK-CC01-A

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关于此项目

经验公式（希尔记法）:
C28H37ClNPPd
化学文摘社编号:
359803-53-5
分子量:
560.45
NACRES:
NA.22
PubChem Substance ID:
57649461
UNSPSC Code:
12161600
MDL number:
MFCD03427335
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assay

≥99.0% (C)

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

mp

160-170 °C (dec.) (lit.)

SMILES string

C1C[C@@H]2C[C@H]1CC2PC3C[C@@H]4CC[C@H]3C4.CN(C)c5ccccc5-c6ccccc6[Pd]Cl

InChI

1S/C14H14N.C14H23P.ClH.Pd/c1-15(2)14-11-7-6-10-13(14)12-8-4-3-5-9-12;1-3-11-5-9(1)7-13(11)15-14-8-10-2-4-12(14)6-10;;/h3-8,10-11H,1-2H3;9-15H,1-8H2;1H;/q;;;+1/p-1/t;9-,10+,11+,12-,13?,14?;;

InChI key

YMZCYRNVJBOOCT-SBADXZPPSA-M

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

用于 C-C 和 C-N 偶联反应（如 Suzuki 偶联、Heck 反应等）的对空气和水分稳定的高活性钯催化剂

Legal Information

与 Solvias AG 联合销售

存储类别

11 - Combustible Solids

wgk

WGK 3

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCD1002
BCBR6621V
BCBL9129V
BCBK2522V
BCBH8681V

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Jean-Philippe Ebran et al.
Journal of the American Chemical Society, 129(21), 6931-6942 (2007-05-04)
A catalyst system was identified which promotes the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes providing a new entry to diene products from simple and readily accessible starting materials. In contrast to our earlier work exploiting P(t-Bu)3
A new generation of air stable, highly active Pd complexes for C--C and C--N coupling reactions with aryl chlorides.
Anita Schnyder et al.
Angewandte Chemie (International ed. in English), 41(19), 3668-3671 (2002-10-09)
A. Indolese, A. Schnyder
Eur. Pat. Appl. (2001)
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全球贸易项目编号

货号GTIN
36037-1G-F04061826652473
36037-5G-F04061833547007