Quality Level
assay
97%
form
liquid
reaction suitability
reagent type: reductant
refractive index
n20/D 1.489 (lit.)
bp
73 °C/5 mmHg (lit.)
density
0.806 g/mL at 25 °C (lit.)
SMILES string
C[Si](C)(C)[SiH]([Si](C)(C)C)[Si](C)(C)C
InChI
1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3
InChI key
SQMFULTZZQBFBM-UHFFFAOYSA-N
General description
三（三甲基硅基）硅烷是一种有机硅，通常作为自由基还原剂，用于黄原酸酯，有机卤化物，异氰化物，硒化物和酰基氯化物。也用于烯烃，炔烃和二烷基酮的硅氢加成。
Application
超甲硅烷基保护基团
可用于：
可用于：
- 氢化硅烷化
- 自由基反应
- 酸性氯化物的还原
- 碳-卤键的还原
- 羰基氢化反应
- 另一种常见应用涉及在与过渡金属和主族元素络合时，三（三甲基甲硅烷基）甲硅烷基（TTMSS或超甲硅烷基）基团的使用
- 最近，超甲硅烷基被用于碳-碳键形成的反应
signalword
Warning
hcodes
Hazard Classifications
Flam. Liq. 3
存储类别
3 - Flammable liquids
flash_point_f
131.0 °F - closed cup
flash_point_c
55 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
商品
Explore methods for molecular monolayers on silicon surfaces, their properties, and applications in molecular electronics and sensing.
相关内容
The Yamamoto group has employed several applications in catalysis.
Synlett, 91-91 (1990)
Tris (trimethylsilyl) silane: an efficient hydrosilylating agent of alkenes and alkynes
Kopping B, et al.
The Journal of Organic Chemistry, 57(14), 3994-4000 (1992)
Changxia Shi et al.
Science advances, 6(34), eabc0495-eabc0495 (2020-09-03)
Three types of seemingly unyielding trade-offs have continued to challenge the rational design for circular polymers with both high chemical recyclability and high-performance properties: depolymerizability/performance, crystallinity/ductility, and stereo-disorder/crystallinity. Here, we introduce a monomer design strategy based on a bridged bicyclic
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 360716-5G | 04061831823943 |
| 360716-25G | 04061831823936 |