方案
99%
mp
97-101 °C (lit.)
官能团
hydroxyl
SMILES字符串
O[C@@H]1CCCC[C@@H]1O
InChI
1S/C6H12O2/c7-5-3-1-2-4-6(5)8/h5-8H,1-4H2/t5-,6+
InChI key
PFURGBBHAOXLIO-OLQVQODUSA-N
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一般描述
据报道,核壳状二氧化硅镍物种纳米颗粒可催化1,2-环己二醇脱氢成儿茶酚。带有顺式-1,2-环己二醇的Cr(V)络合物的晶体结构已被报道。通过氧化葡糖杆菌(ATCC 621)对顺式-1,2-环己二醇的酶促氧化已被报道。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Oxidation of trans-and cis-1, 2-cyclohexanediol by Gluconobacter oxydans.
Adlercreutz P.
Applied Microbiology and Biotechnology, 30(3), 257-263 (1989)
Ruben Bartholomäus et al.
Inorganic chemistry, 52(8), 4282-4292 (2013-03-28)
The stabilization of Cr(V) by biological 1,2-diolato ligands, including carbohydrates, glycoproteins, and sialic acid derivatives, is likely to play a crucial role in the genotoxicity of Cr(VI) and has also been implicated in the antidiabetic effect of Cr(III). Previously, such
Bao-Hui Chen et al.
Dalton transactions (Cambridge, England : 2003), 44(3), 1023-1038 (2014-11-20)
A simple and convenient approach denoted as gel-deposition-precipitation (G-D-P) for the preparation of core-shell-like silica@nickel species nanoparticles was studied systematically. Core-shell-like silica@nickel species nanoparticles consisted of a Si-rich core and a Ni-rich shell. The G-D-P process included two steps: one
Uta Griesenbach et al.
The journal of gene medicine, 14(7), 491-500 (2012-06-20)
The nuclear membrane of differentiated airway epithelial cells is a significant barrier for nonviral vectors. Trans-cyclohexane-1,2-diol (TCHD) is an amphipathic alcohol that has been shown to collapse nuclear pore cores and allow the uptake of macromolecules that would otherwise be
Yoshihito Shiota et al.
Inorganic chemistry, 50(13), 6200-6209 (2011-06-04)
The catalytic conversion of 1,2-cyclohexanediol to adipic anhydride by Ru(IV)O(tpa) (tpa ═ tris(2-pyridylmethyl)amine) is discussed using density functional theory calculations. The whole reaction is divided into three steps: (1) formation of α-hydroxy cyclohexanone by dehydrogenation of cyclohexanediol, (2) formation of
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