361399
四丁基氟化铵 溶液
75 wt. % in H2O
别名:
TBAF 溶液
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关于此项目
线性分子式:
[CH3(CH2)3]4NF
化学文摘社编号:
分子量:
261.46
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3762762
产品名称
四丁基氟化铵 溶液, 75 wt. % in H2O
InChI
1S/C16H36N.FH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
SMILES string
[F-].CCCC[N+](CCCC)(CCCC)CCCC
InChI key
FPGGTKZVZWFYPV-UHFFFAOYSA-M
form
viscous liquid
concentration
75 wt. % in H2O
density
0.953 g/mL at 25 °C
functional group
amine
Quality Level
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Application
用于制备以下试剂的反应物：
- 三重单胺再摄取抑制剂，用作新一代抗抑郁药物
- 在中性pH有机-水混合缓冲溶液中，水解烷基硅醚的醇
- 磷酸盐修饰键的寡核苷酸
- 通过手性双吡啶二醇配体和三氯化铬催化Nozaki-Hiyama烯丙基化反应的芳基烷基醇
- 通过Suzuki偶联反应结合的二烯酸酯
- 具有抗肿瘤作用的大环邻氨基苯扎胺Hsp90抑制剂
- 磷酰肌醇3激酶(PI3K)/哺乳动物雷帕霉素(mTOR)双抑制剂的靶点
- 抗糖尿病聚乙炔糖甙
signalword
Warning
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2
supp_hazards
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Noelia Luque et al.
Journal of chromatography. A, 1248, 74-83 (2012-06-26)
The suitability of a mixed-mode sorbent made up of admicelles of sodium dodecyl sulphate (SDS) and tetrabutylammonium (TBA) to extract and preserve pesticides from river and underground water was assessed. Pesticides belonging to different structural groups (i.e. triazines, carbamates, phenylureas
Shohei Sakashita et al.
Organic letters, 15(17), 4308-4311 (2013-08-21)
Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of tetrabutylammonium 2-pyridyltriolborate salts with various aryl (heteroaryl) chlorides can produce the corresponding desired coupling products with good to excellent yields. These tetrabutylammonium salts are more reactive than the corresponding lithium salts. The coupling reactions with
Kosei Sugahara et al.
Chemical communications (Cambridge, England), 48(67), 8422-8424 (2012-07-14)
A tetra-n-butylammonium (TBA) salt of a γ-Keggin -6-charged germanodecatungstate, [γ-H(2)GeW(10)O(36)](6-) (I), could act as an efficient homogeneous catalyst for Knoevenagel condensation of active methylene compounds with carbonyl compounds.
David J Posson et al.
Nature structural & molecular biology, 20(2), 159-166 (2012-12-25)
Understanding how ion channels open and close their pores is crucial for comprehending their physiological roles. We used intracellular quaternary ammonium blockers, electrophysiology and X-ray crystallography to locate the voltage-dependent gate in MthK potassium channels from Methanobacterium thermoautotrophicum. Blockers bind
Shintaro Itagaki et al.
Chemical communications (Cambridge, England), 48(74), 9269-9271 (2012-08-10)
In the presence of Rh(2)(OAc)(4) (OAc = acetate) and TBA(2)WO(4) (TBA = tetra-n-butylammonium), the N-silylation of indole derivatives with hydrosilanes efficiently proceeded to give the corresponding N-silylated indoles in high yields. Pyrrole and carbazole were also N-silylated with the combined
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