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Merck
CN

362026

Sigma-Aldrich

双(亚乙基二硫醇)四硫代富瓦烯

98%

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别名:
BEDT-TTF, 二[5,6-二氢-1,3-二硫代[4,5-b][1,4]-二噻烯基-2-烯]
经验公式(希尔记法):
C10H8S8
CAS号:
分子量:
384.69
Beilstein:
1653830
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23

质量水平

检测方案

98%

形式

solid

mp

~260 °C (dec.) (lit.)

SMILES字符串

C1CSC2=C(S1)S\C(S2)=C3\SC4=C(SCCS4)S3

InChI

1S/C10H8S8/c1-2-12-6-5(11-1)15-9(16-6)10-17-7-8(18-10)14-4-3-13-7/h1-4H2

InChI key

LZJCVNLYDXCIBG-UHFFFAOYSA-N

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相关类别

一般描述

双(亚乙基二硫醇)四硫代富瓦烯 (BEDT-TTF) 是一种可用作电子供体的有机超导聚合物,其超导转变温度(Tc)为10K。

应用

BEDT-TTF可用作四硫氰酸根合铜(tetrathiocyanatocuprate)的平衡阴离子,后者可通过恒电流电结晶工艺制备。它还可以通过将含锰配合物合成为多功能分子材料,从而制备新型顺磁性导体。BEDT-TTF掺杂可用于制造混合有机电荷产生层,该电荷产生层有望用于串联式有机发光二极管(OLED)的开发中。
用作有机超导体的组分

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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Anion polarity-induced self-doping in a purely organic paramagnetic conductor, α?-α?-(BEDT-TTF) 2 (PO-CONH-m-C6H4SO3)? H2O where BEDT-TTF is bis (ethylenedithio) tetrathiafulvalene and PO is the radical 2, 2, 5, 5-Tetramethyl-3-pyrrolin-1-oxyl.
Akutsu H, et al.
Polyhedron, 136, 23-29 (2017)
Yoshitaka Kawasugi et al.
Science advances, 5(5), eaav7282-eaav7282 (2019-05-17)
A Mott insulator sometimes induces unconventional superconductivity in its neighbors when doped and/or pressurized. Because the phase diagram should be strongly related to the microscopic mechanism of the superconductivity, it is important to obtain the global phase diagram surrounding the
Péter Szirmai et al.
Proceedings of the National Academy of Sciences of the United States of America, 117(47), 29555-29560 (2020-11-07)
The exotic properties of quantum spin liquids (QSLs) have continually been of interest since Anderson's 1973 ground-breaking idea. Geometrical frustration, quantum fluctuations, and low dimensionality are the most often evoked material's characteristics that favor the long-range fluctuating spin state without
Superconductivity in layered organic metals.
Wosnitza J.
Crystals, 2(2), 248-265 (2012)
A new compound in the BEDT-TTF family [BEDT-TTF= bis (ethylenedithio) tetrathiafulvalene] with a tetrathiocyanatocuprate (II) anion,(BEDT-TTF) 4 [Cu (NCS) 4].
Faulmann C, et al.
Acta Crystallographica Section E: Crystallographic Communications, 74(12), 1755-1758 (2018)

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