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363448

4-氯苯丁酮

technical grade

别名:

4-氯-1-苯基-1-丁酮, 对氯苯丁酮

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关于此项目

线性分子式:
C6H5COCH2CH2CH2Cl
化学文摘社编号:
939-52-6
分子量:
182.65
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24862196
EC Number:
213-362-1
Beilstein/REAXYS Number:
878974
MDL number:
MFCD00001005
Form:
liquid
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grade

technical grade

form

liquid

refractive index

n20/D 1.544 (lit.)

mp

19-20 °C (lit.)

density

1.137 g/mL at 25 °C (lit.)

functional group

chloro, ketone, phenyl

SMILES string

ClCCCC(=O)c1ccccc1

InChI

1S/C10H11ClO/c11-8-4-7-10(12)9-5-2-1-3-6-9/h1-3,5-6H,4,7-8H2

InChI key

GHEFQKHLHFXSBR-UHFFFAOYSA-N

General description

4-Chlorobutyrophenone is a chloro ketone. Preparation of 4-chlorobutyrophenone is reported.

Application

4-Chlorobutyrophenone may be used in the preparation of silyl enol ether, Z-4-chloro-1-phenyl-1-trimethylsilyloxybut-1-ene. It may be used as starting material in the preparation of 8-arylimidazopyridines.

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

法规信息

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分析证书(COA)

Lot/Batch Number
MKBB7093V
MKBB7093
MKAA4725
04311JE
02916HD

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William J Kerr et al.
Organic & biomolecular chemistry, 6(7), 1238-1243 (2008-03-26)
Treatment of commercially available MesMgBr with 1,4-dioxane produces the key Mes(2)Mg reagent in situ which then mediates the deprotonation of ketones to deliver trimethylsilyl enol ethers, at readily accessible temperatures and without any nucleophilic addition, in an expedient and high
The Journal of Organic Chemistry, 52, 1863-1863 (1987)
Neighboring group participation by carbonyl oxygen.
Pasto DJ and Serve MP.
Journal of the American Chemical Society, 87(7), 1515-1521 (1965)

全球贸易项目编号

货号GTIN
363448-5G04061836684693