363596
二乙基焦磷酰胺
98%
别名:
(二乙氧基磷酰)胺, O,O′-二乙基磷酰胺, 二乙基磷酰酰胺, 氨基膦酸二乙酯, 脒基磷酸二乙酯
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关于此项目
线性分子式:
H2NP(O)(OC2H5)2
化学文摘社编号:
分子量:
153.12
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
二乙基焦磷酰胺, 98%
Quality Level
InChI
1S/C4H12NO3P/c1-3-7-9(5,6)8-4-2/h3-4H2,1-2H3,(H2,5,6)
SMILES string
CCOP(N)(=O)OCC
InChI key
MCQILDHFZKTBOD-UHFFFAOYSA-N
assay
98%
bp
140 °C/3 mmHg (lit.)
mp
51-53 °C (lit.)
Application
氨基磷酸二乙酯可用作模拟或模仿实际化学战剂的试剂。 它可以通过三组分Mannich型反应用于制备α-氨基烷基膦酸酯。
General description
氨基磷酸二乙酯是一种化学和生物毒素，并且通过表面增强拉曼光谱（SERS）对其进行超低水平检测已有报道。 它被报道为化学战模拟物。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Yan F and Vo-Dinh T.
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The detection of molecules at an ultralow level by Surface-Enhanced Raman Spectroscopy (SERS) has recently attracted enormous interest for various applications especially in biological, medical, and environmental fields. Despite the significant progress, SERS systems are still facing challenges for practical
Surface detection of chemical warfare agent simulants and degradation products.
Kanu AB, et al.
Analytica Chimica Acta, 553(1), 148-159 (2001)
Mannich type reactions of chlorophosphites, phosphoramides and aldehydes (ketones) under solvent-free and catalyst-free conditions-synthesis of N-phosphoramino a-aminophosphonates.
Zhang J, et al.
Green Chemistry, 9(12), 1341-1345 (2007)
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Pesticide biochemistry and physiology, 163, 31-38 (2020-01-25)
Amidase is an important hydrolytic enzyme in detoxification metabolism. Amidase hydrolyzes a wide variety of nonpeptide carbon‑nitrogen bonds by attacking a cyano group or carbonyl carbon. However, little is known about the relationship between amidase and insecticides. In this study
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