产品名称
4-溴苯甲酸乙酯, 98%
InChI key
XZIAFENWXIQIKR-UHFFFAOYSA-N
InChI
1S/C9H9BrO2/c1-2-12-9(11)7-3-5-8(10)6-4-7/h3-6H,2H2,1H3
SMILES string
CCOC(=O)c1ccc(Br)cc1
assay
98%
form
liquid
refractive index
n20/D 1.544 (lit.)
bp
131 °C/14 mmHg (lit.)
density
1.403 g/mL at 25 °C (lit.)
functional group
bromo
ester
Quality Level
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General description
4-溴苯甲酸乙酯是一种具有吸电子取代基的酯。它可在0℃下用二异丁基叔丁氧基氢化铝(PDBBA)还原得到醛。4-溴苯甲酸乙酯和取代的苄基氯与锌粉和Pd催化剂的反应已被报道。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
>235.4 °F - closed cup
flash_point_c
> 113 °C - closed cup
ppe
Eyeshields, Gloves
法规信息
新产品
此项目有
Christophe Duplais et al.
Chemical communications (Cambridge, England), 46(4), 562-564 (2010-01-12)
A remarkably simple entry to unsymmetrical diarylmethanes has been developed that relies on an in situ organozinc-mediated, palladium-catalyzed cross-coupling. Thus, by mixing a benzyl and aryl halide together in the presence of Zn metal and a Pd catalyst, diarylmethanes are
Chemoselective Reduction of Esters to Aldehydes by Potassium Diisobutyl-t-butoxyaluminum Hydride (PDBBA).
Chae MJ, et al.
Bull. Korean Chem. Soc., 28(12), 2517-2517 (2007)
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