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线性分子式:
[C6H5CH(NH2)-]2
化学文摘社编号:
分子量:
212.29
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3201645
Assay:
97%
产品名称
(1S,2S)-(-)-1,2-二苯基乙二胺, 97%
InChI
1S/C14H16N2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14H,15-16H2/t13-,14-/m0/s1
SMILES string
N[C@H]([C@@H](N)c1ccccc1)c2ccccc2
InChI key
PONXTPCRRASWKW-KBPBESRZSA-N
assay
97%
optical activity
[α]20/D −102°, c = 1 in ethanol
optical purity
ee: 98% (GLC)
mp
83-85 °C (lit.)
functional group
amine
phenyl
Quality Level
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Application
形成金属络合物的多功能配体。用于合成在不对称催化中具有应用潜力的 tropocoronand。
General description
1,2-二苯基乙二胺是一种手性分子,通常用作手性拆分剂和手性助剂前体。它还可用作NMR研究的手性溶剂化试剂。
Packaging
无底玻璃瓶。内含物在插入的融合锥体内。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Chiral Reagents for Asymmetric Synthesis (2003)
Mukaiyama, T.
Aldrichimica Acta, 29, 59-59 (1996)
Chenier, P.J. et al.
Tetrahedron Letters, 38, 7341-7341 (1997)
V Larsimont et al.
Journal of pharmaceutical and biomedical analysis, 19(6), 855-864 (2000-03-04)
Two tyrosine specific, HPLC methods with either electrochemical (HPLC-ED) or fluorescence (HPLC-FL) detection are described for leucine-enkephalin (LE) in cerebrospinal fluid (CSF). Both approaches involve the hydroxylation of the Tyr1-moiety of LE by mushroom tyrosinase. Production of a catechol permitted
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