364428
(S)-(-)-香茅酸
98%
别名:
(S)-(-)-3,7-二甲基-6-辛酸
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线性分子式:
(CH3)2C=CHCH2CH2CH(CH3)CH2CO2H
化学文摘社编号:
分子量:
170.25
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
98%
表单
liquid
旋光性
[α]25/D −8°, neat
折射率
n20/D 1.453 (lit.)
沸点
115-120 °C/0.4 mmHg (lit.)
密度
0.926 g/mL at 25 °C (lit.)
官能团
carboxylic acid
SMILES字符串
C[C@@H](CC\C=C(/C)C)CC(O)=O
InChI
1S/C10H18O2/c1-8(2)5-4-6-9(3)7-10(11)12/h5,9H,4,6-7H2,1-3H3,(H,11,12)/t9-/m0/s1
InChI key
GJWSUKYXUMVMGX-VIFPVBQESA-N
应用
(S)-(-)-Citronellic acid may be used in the synthesis of trisubstituted piperidine substructures of the veratramine and jervine type, that can be building blocks for developing cyclopamine analogs.
Philipp Heretsch et al.
Organic letters, 11(23), 5410-5412 (2009-11-04)
All four diastereomers of the trisubstituted piperidine-alkaloids of the veratramine and jervine type were synthesized with complete stereocontrol starting from enantiopure citronellic acids. The flexible, high-yielding, and scalable route described here will facilitate convergent syntheses and give access to analogues
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