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线性分子式:
CCl3C(=NH)OC(CH3)3
化学文摘社编号:
分子量:
218.51
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1770049
Assay:
96%
Quality Level
assay
96%
refractive index
n20/D 1.456 (lit.)
bp
65 °C/11 mmHg (lit.)
mp
21 °C (lit.)
density
1.221 g/mL at 25 °C (lit.)
functional group
chloro, ether
storage temp.
2-8°C
SMILES string
CC(C)(C)OC(=N)C(Cl)(Cl)Cl
InChI
1S/C6H10Cl3NO/c1-5(2,3)11-4(10)6(7,8)9/h10H,1-3H3
InChI key
CQXDYHPBXDZWBA-UHFFFAOYSA-N
Application
2,2,2-三氯乙酰亚胺叔丁酯可用于合成N-α-Fmoc-磷酸(1-硝基苯基乙基-2-氰基乙基)-L-丝氨酸,笼状结构单元。它可用于将醇和羧酸转化为它们各自的醚和酯。
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
131.0 °F - closed cup
flash_point_c
55 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
商品
Trichloroacetimidates are also commonly employed as alcohol alkylation reagents, particularly when existing functionality is not acid sensitive.
Journal of the Chemical Society. Perkin Transactions 1, 2247-2247 (1985)
Deborah M Rothman et al.
The Journal of organic chemistry, 68(17), 6795-6798 (2003-08-16)
Three 1-(2-nitrophenyl)ethyl-caged phospho-amino acids have been synthesized for use in standard N(alpha)-fluorenylmethoxycarbonyl-based solid-phase peptide synthesis (SPPS). The most common naturally occurring phospho-amino acids, serine, threonine, and tyrosine, were prepared as protected caged building blocks by modification with a unique phosphitylating
Tetrahedron Letters, 29, 2483-2483 (1988)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 364789-25G | 04061831825541 |
| 364789-5G | 04061837507366 |

