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Merck
CN

364789

叔丁基 2,2,2-三氯乙酰亚胺酯

96%

别名:

TBTA

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关于此项目

线性分子式:
CCl3C(=NH)OC(CH3)3
化学文摘社编号:
分子量:
218.51
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1770049
Assay:
96%
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Quality Level

assay

96%

refractive index

n20/D 1.456 (lit.)

bp

65 °C/11 mmHg (lit.)

mp

21 °C (lit.)

density

1.221 g/mL at 25 °C (lit.)

functional group

chloro, ether

storage temp.

2-8°C

SMILES string

CC(C)(C)OC(=N)C(Cl)(Cl)Cl

InChI

1S/C6H10Cl3NO/c1-5(2,3)11-4(10)6(7,8)9/h10H,1-3H3

InChI key

CQXDYHPBXDZWBA-UHFFFAOYSA-N

Application

2,2,2-三氯乙酰亚胺叔丁酯可用于合成N-α-Fmoc-磷酸(1-硝基苯基乙基-2-氰基乙基)-L-丝氨酸,笼状结构单元。它可用于将醇和羧酸转化为它们各自的醚和酯。


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pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

131.0 °F - closed cup

flash_point_c

55 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Trichloroacetimidates are also commonly employed as alcohol alkylation reagents, particularly when existing functionality is not acid sensitive.


Journal of the Chemical Society. Perkin Transactions 1, 2247-2247 (1985)
Deborah M Rothman et al.
The Journal of organic chemistry, 68(17), 6795-6798 (2003-08-16)
Three 1-(2-nitrophenyl)ethyl-caged phospho-amino acids have been synthesized for use in standard N(alpha)-fluorenylmethoxycarbonyl-based solid-phase peptide synthesis (SPPS). The most common naturally occurring phospho-amino acids, serine, threonine, and tyrosine, were prepared as protected caged building blocks by modification with a unique phosphitylating
Tetrahedron Letters, 29, 2483-2483 (1988)



全球贸易项目编号

货号GTIN
364789-25G04061831825541
364789-5G04061837507366