365386
二异丙基甲胺酰氯
98%
别名:
Diisopropylcarbamic chloride, Diisopropylcarbamyl chloride, N,N-Bis(1-methylethyl)carbamic chloride
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关于此项目
线性分子式:
[(CH3)2CH]2NCOCl
化学文摘社编号:
分子量:
163.65
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
242-743-5
Beilstein/REAXYS Number:
1754834
MDL number:
Assay:
98%
Form:
solid
InChI key
RSAFAYLZKCYUQW-UHFFFAOYSA-N
InChI
1S/C7H14ClNO/c1-5(2)9(6(3)4)7(8)10/h5-6H,1-4H3
SMILES string
CC(C)N(C(C)C)C(Cl)=O
assay
98%
form
solid
bp
90-93 °C/15 mmHg (lit.)
Quality Level
functional group
amine, chloro
Application
N,N-Diisopropylcarbamoyl chloride may be used in the preparation of:
- 1-aryl-1-alkenyl N,N-diisopropylcarbamates
- 1,3-diphenylallyl carbamate
- (Z)-1,3-diphenyl-1-propenyl N,N-diisopropylcarbamate
- (R)-1-(2-methoxy-4-methylphenyl)ethyl diisopropyl-carbamate
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Asymmetric ?-Deprotonation and Substitution Reactions of (Z)-1, 3-Diphenyl-1-propenyl N, N-Diisopropylcarbamate.
Reuber J, et al.
European Journal of Organic Chemistry, 14, 3017-3025 (2005)
The total synthesis of (-)-aplysin via a lithiation-borylation-propenylation sequence.
Fletcher CJ, et al.
Tetrahedron, 68(23), 7598-7604 (2012)
Stereoselective Intermolecular Carbolithiation of Open-Chain and Cyclic 1-Aryl-1-alkenyl N,N-Diisopropylcarbamates Coupled with Electrophilic Substitution. Observation of p-Carboxylation in a Benzyllithium Derivative.
Peters JG, et al.
Synthesis, 03, 0381-0292 (2002)
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