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366404

1,1,4,7,10,10-六甲基三亚乙基四胺

97%

别名:

HMTETA

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关于此项目

线性分子式:
[(CH3)2NCH2CH2N(CH3)CH2-]2
化学文摘社编号:
3083-10-1
分子量:
230.39
NACRES:
NA.22
PubChem Substance ID:
24862651
UNSPSC Code:
12352100
EC Number:
221-382-7
MDL number:
MFCD00025684
Assay:
97%
Form:
liquid
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Quality Level

100

assay

97%

form

liquid

refractive index

n20/D 1.456 (lit.)

bp

130 °C/11 mmHg (lit.)

density

0.847 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CN(C)CCN(C)CCN(C)CCN(C)C

InChI

1S/C12H30N4/c1-13(2)7-9-15(5)11-12-16(6)10-8-14(3)4/h7-12H2,1-6H3

InChI key

DWFKOMDBEKIATP-UHFFFAOYSA-N

General description

1,1,4,7,10,10-六甲基三乙烯四胺是一种多胺添加剂，已被报告为问题 Koenigs-Knorr 葡萄糖醛酸化的有效试剂。

Application

1,1,4,7,10,10-六甲基三乙烯四胺可用来合成理想的线性无规共聚物。1,1,4,7,10,10-六甲基三乙烯四胺与 CuBr 形成催化络合物，用于原子转移自由基聚合法 (ATRP) 合成聚 [ε-己内酯] 与 N,N-二甲氨基-2-乙基甲基丙烯酸酯单体。它可以作为水溶液中的催化剂，在表面引发的 ATRP 中生成聚 N,N -二甲基丙烯酰胺 (PDMA)。

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

215.6 °F - closed cup

flash_point_c

102 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCV3348
MKCR6686
MKCM9494
MKCJ8395
MKCD2394

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实验方案

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Stefanie L Baker et al.
Nature communications, 10(1), 4718-4718 (2019-10-19)
Almost all commercial proteins are purified using ammonium sulfate precipitation. Protein-polymer conjugates are synthesized from pure starting materials, and the struggle to separate conjugates from polymer, native protein, and from isomers has vexed scientists for decades. We have discovered that
Bryan R Coad et al.
Langmuir : the ACS journal of surfaces and colloids, 23(23), 11791-11803 (2007-10-11)
We report the use of aqueous surface-initiated atom transfer radical polymerization (SI-ATRP) to grow polymer brushes from a "gigaporous" polymeric chromatography support for use as a novel size exclusion chromatography medium. Poly(N,N-dimethylacrylamide) (PDMA) was grown from hydrolyzable surface initiators via
Laetitia Mespouille et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(21), 6369-6378 (2008-06-10)
Adaptive and amphiphilic poly(N,N-dimethylamino-2-ethyl methacrylate-graft-poly[epsilon-caprolactone]) co-networks (netP(DMAEMA-g-PCL)) were synthesized from a combination of controlled polymerization techniques. Firstly, PCL cross-linkers were produced by ring-opening polymerization (ROP) of epsilon-CL initiated by 1,4-butane-diol and catalyzed by tin(II) 2-ethylhexanoate ([Sn(Oct)2]), followed by the quantitative
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货号GTIN
366404-25G04061836832155
366404-5G04061831826104