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Merck
CN

367672

2,2-双(4-羧基苯基)六氟丙烷

98%

别名:

2,2-双(4-二羧基苯基)-1,1,1,3,3,3-六氟丙烷, 2,2-双(对羧基苯基)六氟丙烷, 4,4′-[2,2,2-三氟-1-(三氟甲基)乙基亚乙基]双[苯甲酸], 4,4′-六氟异亚丙基二苯基l-1,1′-二羧酸, 4,4′-(1,1,1,3,3,3-六氟丙烷-2,2-二基)二苯甲酸, 六氟-2,2-双(4-羧基苯基)丙烷

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关于此项目

线性分子式:
(CF3)2C(C6H4CO2H)2
化学文摘社编号:
分子量:
392.25
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
98%
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Quality Level

assay

98%

mp

272-274 °C (lit.)

functional group

carboxylic acid, fluoro

SMILES string

OC(=O)c1ccc(cc1)C(c2ccc(cc2)C(O)=O)(C(F)(F)F)C(F)(F)F

InChI

1S/C17H10F6O4/c18-16(19,20)15(17(21,22)23,11-5-1-9(2-6-11)13(24)25)12-7-3-10(4-8-12)14(26)27/h1-8H,(H,24,25)(H,26,27)

InChI key

PHQYMDAUTAXXFZ-UHFFFAOYSA-N

General description

4,4′-(六氟异亚丙基)双(苯甲酸)是一种芳族二羧酸。它是一种多用途的配体。

Application

4,4′-(六氟异亚丙基)双(苯甲酸)适合用作聚恶二唑和聚三唑的合成单体。可用于:
  • 溶剂热合成带有不同过渡金属离子的新配位化合物
  • 用作金属有机配位聚合物溶剂热合成中的弯曲配体
  • 合成RPF-4(一种聚合骨架家族)


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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Felipe Gándara et al.
Inorganic chemistry, 48(11), 4707-4713 (2009-04-21)
RPF-4 is a family of polymeric frameworks prepared with rare-earth elements and the versatile ligand 4,4'-(hexafluoroisopropylidene)bis(benzoic acid). We have found that during the synthesis procedure up to three different polymorphs can be obtained. Their crystal structures are here presented. The
Wenbin Yang et al.
Inorganic chemistry, 48(23), 11067-11078 (2009-12-01)
We have synthesized five new metal-organic coordination polymers incorporating the bent ligand H(2)hfipbb [4,4'-(hexafluoroisopropylidene)bis(benzoic acid)] with different transition metal ions and co-ligands via solvothermal reactions to give [Zn(2)(hfipbb)(2)(py)(2)] x DMF (1), [Zn(2)(hfipbb)(2)(4,4'-bipy)(H(2)O)] (2), [Zn(2)(hfipbb)(2)(bpdab)].2DMF (3), [Cd(2)(hfipbb)(2)(DMF)(2)] x 2 DMF (4)
Sheida Esmaielzadeh et al.
Ultrasonics sonochemistry, 41, 641-650 (2017-11-16)
Novel sulfonated polybenzimidazole (s-PBI)/cellulose/silica bionanocomposite membranes were prepared from fluorine-containing s-PBI copolymer with a cellulose/silica precursor and a bonding agent. The introduction of the bonding agent results in the reinforcing interfacial interaction between s-PBI chains and the cellulose/silica nanoparticles. Commercially



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货号GTIN
367672-5G04061831827477