369047
(叔丁氧基羰基甲基)溴化三苯基磷
98%
别名:
NSC 82468
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关于此项目
线性分子式:
(CH3)3CO2CCH2P(C6H5)3Br
化学文摘社编号:
分子量:
459.36
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352108
MDL number:
产品名称
(叔丁氧基羰基甲基)溴化三苯基磷, 98%
InChI
1S/C24H26O2P.BrH/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-18H,19H2,1-3H3;1H/q+1;/p-1
SMILES string
[Br-].CC(C)(C)OC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI key
ZGLFRTJDWWKIAK-UHFFFAOYSA-M
assay
98%
reaction suitability
reaction type: C-C Bond Formation
mp
178 °C (dec.) (lit.)
functional group
ester
phosphine
Quality Level
Application
Reactant for:
- Rhodium-catalyzed asymmetric hydrogenation reactions
- Wittig reaction
- Wittig methylenation
- Preparation of N-(phenylmethyl)-cis-pyrrolidinediacetic acid esters via double aza-Michael addition reaction
- Stereoselective preparation of of α-fluoro-α,β-unsaturated esters via deprotonation, followed by fluorination and stereoselective Wittig olefination with aldehydes
- Wittig chain extension reactions
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
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