Merck
CN

369306

Sigma-Aldrich

3-硝基邻苯二甲酸

95%

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线性分子式:
O2NC6H3-1,2-(CO2H)2
CAS号:
分子量:
211.13
Beilstein:
2054269
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

95%

mp

210 °C (dec.) (lit.)

溶解性

water: soluble 5%, clear to slightly hazy, colorless to faintly yellow

SMILES string

OC(=O)c1cccc(c1C(O)=O)[N+]([O-])=O

InChI

1S/C8H5NO6/c10-7(11)4-2-1-3-5(9(14)15)6(4)8(12)13/h1-3H,(H,10,11)(H,12,13)

InChI key

KFIRODWJCYBBHY-UHFFFAOYSA-N

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137820274755117714
3-Nitrophthalic acid 95%

Sigma-Aldrich

369306

3-硝基邻苯二甲酸

3-Nitrophthalic acid 99%

Sigma-Aldrich

137820

3-硝基邻苯二甲酸

4-Nitrophthalic acid 92%

Sigma-Aldrich

274755

4-硝基邻苯二甲酸

3-Methoxybenzoic acid ReagentPlus®, 99%

Sigma-Aldrich

117714

3-甲氧基苯甲酸

mp

210 °C (dec.) (lit.)

mp

210 °C (dec.) (lit.)

mp

159-161 °C (lit.)

mp

105-107 °C (lit.)

solubility

water: soluble 5%, clear to slightly hazy, colorless to faintly yellow

solubility

water: soluble 5%, clear to slightly hazy, colorless to faint yellow or tan

solubility

-

solubility

95% ethanol: soluble 50 mg/mL, clear, colorless to faintly yellow

一般描述

3-硝基邻苯二甲酸是一种异恶唑除草剂的降解产物。它作为配体可与La、Nd、Eu、Tb、Er和Y形成稀土络合物。3-硝基邻苯二甲酸的制备已被报道。

应用

3-硝基邻苯二甲酸可被用作合成改性的2-碘代苯甲酸衍生物的起始试剂。它可通过与亮氨酸加热合成2-羧基-6-硝基邻苯二甲酸溴化物二水合物(系统名称:2,3-二甲氧基-10-氧代噻吩-2-羰基-6-硝基邻苯二甲酸酯二水合物)。

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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Brucinium 2-carboxy-6-nitrophthalate dihydrate: the 1: 1 proton-transfer compound of brucine with 3-nitrophthalic acid.
Smith G, et al.
Acta Crystallographica Section E, Structure Reports Online, 61(7), o2008-o2011 (2005)
The preparation of 3-nitrophthalic acid.
Littmann ER.
Journal of the American Chemical Society, 47(7), 1980-1981 (1925)
Fan Zhang et al.
Guang pu xue yu guang pu fen xi = Guang pu, 29(10), 2773-2776 (2009-12-30)
A series of rare-earth compound RE2L2 (HL)2 (H2O)6 x 2H2O (RE=La, Nd, Eu, Tb, Er, Y) containing 3-nitrophthalic acid (H2L) ligand were synthesized from ethanol-water solution, and characterized and investigated by the element analysis, infrared and ultraviolet absorption spectra and
Hypervalent iodine reagents for the oxidation of alcohols and their application to complex molecule synthesis.
Tohma H and Kita Y.
Advanced Synthesis & Catalysis, 346(2-3), 111-124 (2004)
Clyatt E Drakeford et al.
Chemosphere, 50(9), 1243-1247 (2003-01-28)
Commercial production of ornamental plants is an important industry in the United States and involves a complex technology that includes the use of herbicides. Isoxaben[N-[3-(1-ethyl-1-methylpropyl)-5-isoxazolyl]-2,6-dimethoxybenzamide] is a pre-emergence herbicide used for controlling weeds in many areas including containerized ornamental plants.

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