N-叔丁基三甲基硅基胺

Name: <I>N</I>-叔丁基三甲基硅基胺
Brand: ALDRICH

98%

别名:

N-(三甲基硅基)-叔丁胺

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所有图片(1)

About This Item

线性分子式:

(CH₃)₃SiNHC(CH₃)₃

CAS Number:

5577-67-3

分子量:

145.32

Beilstein:

1734528

MDL编号:

MFCD00054891

UNSPSC代码:

12352100

PubChem化学物质编号:

24862959

NACRES:

NA.22

质量水平

100

方案

98%

表单

liquid

折射率

n20/D 1.406 (lit.)

沸点

118-119 °C (lit.)

密度

0.762 g/mL at 25 °C (lit.)

官能团

amine

SMILES字符串

CC(C)(C)N[Si](C)(C)C

InChI

1S/C7H19NSi/c1-7(2,3)8-9(4,5)6/h8H,1-6H3

InChI key

GVHIREZHTRULPT-UHFFFAOYSA-N

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一般描述

N-tert-Butyltrimethylsilylamine (Me₃SiNH-t-Bu) reacts with [Cp*Rh(H₂O)₃](OTf)₂ in acetone to yield a hydroxyl-capped half-cubane [Cp*3Rh₃(μ-OH)3(μ₃-OH)](OTf)₃(t-BuNH₃).

应用

N-tert-Butyltrimethylsilylamine may be used in the preparation of selenium and tellurium chalcogenides and the facile synthesis of N-alkylaminomethylphosphonates.