371173
丙酮酸甲酯
90%, technical grade
别名:
甲基丙酮酸酯
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关于此项目
线性分子式:
CH3COCO2CH3
化学文摘社编号:
分子量:
102.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-987-4
Beilstein/REAXYS Number:
1361953
MDL number:
产品名称
丙酮酸甲酯, 90%, technical grade
InChI key
CWKLZLBVOJRSOM-UHFFFAOYSA-N
InChI
1S/C4H6O3/c1-3(5)4(6)7-2/h1-2H3
SMILES string
COC(=O)C(C)=O
grade
technical grade
assay
90%
form
liquid
refractive index
n20/D 1.404 (lit.)
bp
134-137 °C (lit.)
solubility
ethanol: soluble 1.1 g/10 mL, clear, colorless to almost colorless
density
1.13 g/mL at 25 °C (lit.)
functional group
ester
ketone
storage temp.
2-8°C
Quality Level
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Application
丙酮酸甲酯可用于研究丙酮酸甲酯在 Pt{111} 上的吸附和反应性。可用于 2,3-二甲基丁二酸二甲酯的制备。
General description
丙酮酸甲酯是丙酮酸酯。研究了辛可尼丁修饰的 Pt/sio2/EUROPT-1 催化剂上丙酮酸甲酯对映选择性加氢生成 R -(+)-乳酸甲酯的表面条件。研究了丙酮酸甲酯在聚乙烯吡咯烷酮稳定的细分散体上的不对称加氢反应及相应的的辛可尼丁修饰的氧化铝负载铱团簇。研究了在 105-220K 温度范围内丙酮酸甲酯在 Ni (111) 表面的分子取向和构象。据报道，丙酮酸甲酯在体外和体内可刺激胰岛素分泌。
Enantioselective hydrogenation of methyl pyruvate over polymer-stabilized and supported iridium clusters.
Zuo X, et al.
J. Mol. Catal. A: Chem., 147(1), 63-72 (1999)
Fundamental aspects of enantioselective heterogeneous catalysis: the surface chemistry of methyl pyruvate on Pt {111}.
The Journal of Physical Chemistry B, 104(41), 9696-9703 (2000)
Orientation and conformation of methyl pyruvate on Ni (111).
Castonguay M, et al.
Journal of the American Chemical Society, 122(3), 518-524 (2000)
Young-Ra Cho et al.
Molecular oncology, 12(7), 1203-1215 (2018-05-24)
Matrine is a natural compound extracted from the herb Sophora flavescens Ait which is widely used in traditional Chinese medicine for treating various diseases. Recently, matrine was reported to have antitumor effects against a variety of cancers without any obvious
N Lembert et al.
The Biochemical journal, 354(Pt 2), 345-350 (2001-02-15)
The role of mitochondria in stimulus-secretion coupling of pancreatic beta-cells was examined using methyl pyruvate (MP). MP stimulated insulin secretion in the absence of glucose, with maximal effect at 5 mM. K+ (30 mM) alone, or in combination with diazoxide
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