371343
4-苄酰氧基-四甲基哌啶氧自由基
97%
别名:
4-苄酰氧基-四甲基哌啶氧自由基, 4-苯甲酰氧基-2,2,6,6-四甲基哌啶-1-氧基自由基
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关于此项目
经验公式（希尔记法）:
C16H22NO3
化学文摘社编号:
分子量:
276.35
UNSPSC Code:
12352000
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1431263
Assay:
97%
Form:
solid
Quality Segment
assay
97%
form
solid
mp
99-101 °C (lit.)
functional group
ester, phenyl
SMILES string
CC1(C)CC(CC(C)(C)N1[O])OC(=O)c2ccccc2
InChI
1S/C16H22NO3/c1-15(2)10-13(11-16(3,4)17(15)19)20-14(18)12-8-6-5-7-9-12/h5-9,13H,10-11H2,1-4H3
InChI key
MJEDTBDGYVATPI-UHFFFAOYSA-N
General description
4-Hydroxy-TEMPO benzoate is a 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivative.
Application
次氯酸盐/亚溴酸盐-硝基氧氧化体系的循环催化剂，该体系用于醇转化生成醛、酮和羧酸。它避开了催化或化学计量重金属氧化剂的使用。
4-Hydroxy-TEMPO benzoate was employed as spin probe to investigate the mechanism of synthesis of SBA-15 and to evaluate its surface properties and pore structure by electron paramagnetic resonance spectroscopy (EPR). It was also used for the functionalization of various polydienes (polybutadiene and polyisoprene). Functionalized polydienes were analyzed by gel permeation chromatography.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)