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371440

（1- 叔 -丁基乙烯氧基）三甲基硅烷

98%

别名:

(2,2-二甲基-1-亚甲基丙氧基)三甲基硅烷, 3,3-二甲基-2-三甲基硅氧基-1-丁烯, 频哪酮烯醇三甲基硅基醚

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关于此项目

线性分子式:
(CH3)3CC(=CH2)OSi(CH3)3
化学文摘社编号:
17510-46-2
分子量:
172.34
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24863107
MDL number:
MFCD00075567
Beilstein/REAXYS Number:
2204704
Assay:
98%
Form:
liquid
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assay

98%

form

liquid

refractive index

n20/D 1.409 (lit.)

bp

140-142 °C (lit.)

density

0.798 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)C(=C)O[Si](C)(C)C

InChI

1S/C9H20OSi/c1-8(9(2,3)4)10-11(5,6)7/h1H2,2-7H3

InChI key

PEHJULPJEVIIFJ-UHFFFAOYSA-N

General description

(1-tert-Butylvinyloxy)trimethylsilane is a silyl enol. It belongs to organosilicone class of compounds. Enthalpy of vaporization of (1-tert-Butylvinyloxy)trimethylsilane at boiling point has been reported.

Application

(1-tert-Butylvinyloxy)trimethylsilane ((2,2-Dimethyl-1-methylenepropoxy)trimethylsilane) may be used in the synthesis of cis-3,3-dimethyl-1-(6-phenethyl-3,6-dihydro-2H-pyran-2-yl)butan-2-one.
(1-tert-Butylvinyloxy)trimethylsilane may be used in the preparation of 1-(4-bromophenyl)-4,4-dimethylpentan-3-one.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

75.2 °F - closed cup

flash_point_c

24 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCH3796
MKBS7861V
MKBB2546
16424KH
02720LE

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Salvatore Ferla et al.
Journal of medicinal chemistry, 57(18), 7702-7715 (2014-08-26)
The synthesis of imidazole styrylbenzamide, tert-butyl styrylimidazole, and tert-butyl styrylsulfonate derivatives is described. Evaluation of binding affinity and inhibitory activity against CYP24A1 identified the imidazole styrylbenzamides as potent inhibitors of CYP24A1, having selectivity with respect to CYP27B1 comparable with or
Yaws CL.
Thermophysical Properties of Chemicals and Hydrocarbons, 574-574 (2014)
Robert J Hinkle et al.
Tetrahedron, 65(34), 6834-6839 (2010-02-18)
The rapid synthesis of cis-2,6-disubstituted dihydropyrans is achieved in a three-component, one-pot cascade reaction. BiBr(3)-ediated addition of ketene silyl acetals or silyl enol ethers to beta,gamma-unsaturated cis-4-trimethylsilyl-3-butenal provides a Mukaiyama aldol adduct containing a vinylsilane moiety tethered to a silyl

全球贸易项目编号

货号GTIN
371440-5G04061837678721