371440
（1- 叔 -丁基乙烯氧基）三甲基硅烷
98%
别名:
(2,2-二甲基-1-亚甲基丙氧基)三甲基硅烷, 3,3-二甲基-2-三甲基硅氧基-1-丁烯, 频哪酮烯醇三甲基硅基醚
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关于此项目
线性分子式:
(CH3)3CC(=CH2)OSi(CH3)3
化学文摘社编号:
分子量:
172.34
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2204704
Assay:
98%
Form:
liquid
产品名称
（1- 叔 -丁基乙烯氧基）三甲基硅烷, 98%
InChI
1S/C9H20OSi/c1-8(9(2,3)4)10-11(5,6)7/h1H2,2-7H3
SMILES string
CC(C)(C)C(=C)O[Si](C)(C)C
InChI key
PEHJULPJEVIIFJ-UHFFFAOYSA-N
assay
98%
form
liquid
refractive index
n20/D 1.409 (lit.)
bp
140-142 °C (lit.)
density
0.798 g/mL at 25 °C (lit.)
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Application
(1-tert-Butylvinyloxy)trimethylsilane ((2,2-Dimethyl-1-methylenepropoxy)trimethylsilane) may be used in the synthesis of cis-3,3-dimethyl-1-(6-phenethyl-3,6-dihydro-2H-pyran-2-yl)butan-2-one.
(1-tert-Butylvinyloxy)trimethylsilane may be used in the preparation of 1-(4-bromophenyl)-4,4-dimethylpentan-3-one.
General description
(1-tert-Butylvinyloxy)trimethylsilane is a silyl enol. It belongs to organosilicone class of compounds. Enthalpy of vaporization of (1-tert-Butylvinyloxy)trimethylsilane at boiling point has been reported.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
75.2 °F - closed cup
flash_point_c
24 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Yaws CL.
Thermophysical Properties of Chemicals and Hydrocarbons, 574-574 (2014)
Salvatore Ferla et al.
Journal of medicinal chemistry, 57(18), 7702-7715 (2014-08-26)
The synthesis of imidazole styrylbenzamide, tert-butyl styrylimidazole, and tert-butyl styrylsulfonate derivatives is described. Evaluation of binding affinity and inhibitory activity against CYP24A1 identified the imidazole styrylbenzamides as potent inhibitors of CYP24A1, having selectivity with respect to CYP27B1 comparable with or
Robert J Hinkle et al.
Tetrahedron, 65(34), 6834-6839 (2010-02-18)
The rapid synthesis of cis-2,6-disubstituted dihydropyrans is achieved in a three-component, one-pot cascade reaction. BiBr(3)-ediated addition of ketene silyl acetals or silyl enol ethers to beta,gamma-unsaturated cis-4-trimethylsilyl-3-butenal provides a Mukaiyama aldol adduct containing a vinylsilane moiety tethered to a silyl
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