375276
亚胺二羧酸二叔丁酯
≥96%
别名:
N-Boc-氨基甲酸叔丁酯, 亚氨二甲酸二叔丁酯
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关于此项目
线性分子式:
[(CH3)3COCO]2NH
化学文摘社编号:
分子量:
217.26
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1911172
Assay:
≥96%
产品名称
亚胺二羧酸二叔丁酯, ≥96%
InChI
1S/C10H19NO4/c1-9(2,3)14-7(12)11-8(13)15-10(4,5)6/h1-6H3,(H,11,12,13)
SMILES string
CC(C)(C)OC(=O)NC(=O)OC(C)(C)C
InChI key
XCAQIUOFDMREBA-UHFFFAOYSA-N
assay
≥96%
mp
114-117 °C (lit.)
functional group
amine
Quality Level
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Application
Di-tert-butyl-iminodicarboxylate may be used in the preparation of:
- trans-diamino-2-butene and cis-1,4-diamino-2-butene
- di-tert-butyl N-3-butenyliminodicarboxylate
- N,N-di-tert-butyl[(2-fluoro-4-nitro)benzylamino]dicarboxylate
- C1-C20 and C21-C40 fragments of tetrafibricin
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Boyle TP, et al.
Tetrahedron, 61(30), 7271-7276 (2005)
Venugopal Gudipati et al.
Tetrahedron letters, 52(17), 2254-2257 (2011-05-24)
Efficient syntheses of suitably functionalized top and bottom fragments of tetrafibricin are described. The bottom fragment is prepared by two consecutive Kocienski-Julia couplings, while the top fragment synthesis features a dithiane alkylation and a Horner-Wadsworth-Emmons reaction.
K Kashiwagi et al.
The Journal of biological chemistry, 275(46), 36007-36012 (2000-08-31)
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Young Ah Kim et al.
Biochemical pharmacology, 73(10), 1558-1572 (2007-02-20)
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