375691
2-羟亚氨基-2-苯乙腈，顺反异构体混合物
97%
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关于此项目
线性分子式:
C6H5C(=NOH)CN
化学文摘社编号:
分子量:
146.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
212-546-9
MDL number:
Assay:
97%
InChI key
MJCQFBKIFDVTTR-UHFFFAOYSA-N
InChI
1S/C8H6N2O/c9-6-8(10-11)7-4-2-1-3-5-7/h1-5,11H
SMILES string
ON=C(C#N)c1ccccc1
assay
97%
mp
128-130 °C (lit.)
functional group
amine, nitrile, oxime, phenyl
Quality Level
Application
2-Hydroxyimino-2-phenylacetonitrile may be used in the synthesis of 2-t-butoxycarbonyloxyimino-2-phenylacetonitrile and o-chlorobenzyloxycarbonylimino-2-phenylacetonitrile.
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
D Scott Bohle et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(13), 4223-4229 (2013-02-13)
The reaction of nitric oxide with benzyl cyanide in the presence of potassium methoxide at low temperature gave the dipotassium salt of a bis-diazeniumdiolate 2 in excellent yield. Two new stereospecific syntheses of E or Z 2-(hydroxyimino)-2-phenylacetonitrile from 2 have
Refinement of the crystal structure of 2-hydroxyimino-2-phenylacetonitrile, C8H6N2O, at 173 ?.
Razzino P, et al.
Zeitschrift fur Kristallographie - New Crystal Structures, 216(1-4), 583-584 (2001)
A facile method for the preparation of oxime t-butyl carbonates for evaluation of the Beckman rearrangement.
Mamaghani M and Samimi HA.
Orient. J. Chem., 24(3), 837-841 (2008)
THE SYNTHESIS OF j> METHOXYBENZYLOXYCARBONYL AMINO ACIDS.
Wang K-T.
J. Chin. Chem. Soc., 34, 117-123 (1987)
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