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Merck
CN

376159

(三甲基硅基)甲基化异腈

97%

别名:

(异氰甲基)三甲基硅烷

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关于此项目

线性分子式:
(CH3)3SiCH2NC
化学文摘社编号:
30718-17-3
分子量:
113.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24863423
MDL number:
MFCD00043056
Beilstein/REAXYS Number:
3930556
Assay:
97%
Form:
liquid

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InChI

1S/C5H11NSi/c1-6-5-7(2,3)4/h5H2,2-4H3

SMILES string

C[Si](C)(C)C[N+]#[C-]

InChI key

OLSTVZKPVGMQKB-UHFFFAOYSA-N

assay

97%

form

liquid

refractive index

n20/D 1.416 (lit.)

bp

52-53 °C/35 mmHg (lit.)

density

0.803 g/mL at 25 °C (lit.)

functional group

amine, isonitrile

storage temp.

−20°C

Quality Level

200

相关类别

General description

Synthesis of (trimethylsilyl)methyl isocyanide and its reaction with protic nucleophiles has been reported. An improved preparation of (trimethylsilyl)methyl isocyanide is reported. Reaction of (trimethylsilyl)methyl isocyanide with (η2-formaldehyde)zirconocene complex is reported to yield insertion products.

Application

(Trimethylsilyl)methyl isocyanide may be used in the preparation of isocyanomethylenetriphenylphosphorane.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

pictograms

FlameSkull and crossbones
GHS02,GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

<59.0 °F - closed cup

flash_point_c

< 15 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBG0627V
1375040
05628JE
11312KD
18030DO

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An Improved Synthesis of Trimethylsilylmethyl Isocyanide.
Brouwer AC and Van Leusen AM.
Synthetic Communications, 16(8), 865-869 (1986)
A (η1-iminoacyl) zirconocene complex formed by alkyl isocyanide insertion into the metal-to-carbon bond of (η2-formaldehyde) zirconocene.
Erker G, et al.
Organometallics, 10(4), 1201-1203 (1991)
An improved synthesis of trimethylsilylmethyl isocyanide and some of its reactions with nucleophiles.
Smith R and Livinghouse T.
Synthetic Communications, 14(7), 639-646 (1984)
Isocyanomethylenetriphenylphosphorane.
Zinner G and Fehlhammer WP.
Angewandte Chemie (International Edition in English), 24(11), 979-980 (1985)

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