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376159

(三甲基硅基)甲基化异腈

Name: (三甲基硅基)甲基化异腈
Brand: ALDRICH

97%

别名:

(异氰甲基)三甲基硅烷

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关于此项目

线性分子式:

(CH₃)₃SiCH₂NC

化学文摘社编号:

30718-17-3

分子量:

113.23

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24863423

MDL number:

MFCD00043056

Beilstein/REAXYS Number:

3930556

Assay:

97%

Form:

liquid

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属性

Quality Level

200

assay

97%

form

liquid

refractive index

n20/D 1.416 (lit.)

bp

52-53 °C/35 mmHg (lit.)

density

0.803 g/mL at 25 °C (lit.)

functional group

amine, isonitrile

storage temp.

−20°C

SMILES string

C[Si](C)(C)C[N+]#[C-]

InChI

1S/C5H11NSi/c1-6-5-7(2,3)4/h5H2,2-4H3

InChI key

OLSTVZKPVGMQKB-UHFFFAOYSA-N

说明

General description

Synthesis of (trimethylsilyl)methyl isocyanide and its reaction with protic nucleophiles has been reported. An improved preparation of (trimethylsilyl)methyl isocyanide is reported. Reaction of (trimethylsilyl)methyl isocyanide with (η²-formaldehyde)zirconocene complex is reported to yield insertion products.

Application

(Trimethylsilyl)methyl isocyanide may be used in the preparation of isocyanomethylenetriphenylphosphorane.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Disclaimer

Supply conditions do not apply to the regions and states of Brazil: North, Northeast, Mato Grosso do Sul, Mato Grosso, and Rio Grande do Sul.

pictograms

GHS02,GHS06

signalword

Danger

hcodes

H225,H301 + H311 + H331

pcodes

P210 - P233 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

<59.0 °F - closed cup

flash_point_c

< 15 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A (η¹-iminoacyl) zirconocene complex formed by alkyl isocyanide insertion into the metal-to-carbon bond of (η²-formaldehyde) zirconocene.

Erker G, et al.

Organometallics, 10(4), 1201-1203 (1991)

An Improved Synthesis of Trimethylsilylmethyl Isocyanide.

Brouwer AC and Van Leusen AM.

Synthetic Communications, 16(8), 865-869 (1986)

Isocyanomethylenetriphenylphosphorane.

Zinner G and Fehlhammer WP.

Angewandte Chemie (International Edition in English), 24(11), 979-980 (1985)

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全球贸易项目编号

货号	GTIN
376159-500MG	04061837633676