376310
反式-3-(三甲基硅基)烯丙醇
96%
别名:
反式-(3-羟基-2-丙烯-1-基)三甲基硅烷, 反式-3-(三甲基硅基)-2-丙烯-1-醇
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关于此项目
线性分子式:
(CH3)3SiCH=CHCH2OH
化学文摘社编号:
分子量:
130.26
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1902497
产品名称
反式-3-(三甲基硅基)烯丙醇, 96%
InChI
1S/C6H14OSi/c1-8(2,3)6-4-5-7/h4-5,7H,6H2,1-3H3/b5-4+
SMILES string
C[Si](C)(C)C\C=C\O
InChI key
JKKTXDCTGMUFBS-SNAWJCMRSA-N
assay
96%
form
liquid
impurities
<3.5% 3-trimethylsilyl-1-propanol
refractive index
n20/D 1.444 (lit.)
bp
166-168 °C (lit.)
density
0.848 g/mL at 25 °C (lit.)
functional group
aldehyde
storage temp.
−20°C
Quality Level
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Application
trans-3-(Trimethylsilyl)allyl alcohol is suitable for use in the preparation of 1-iodo-3-trimethylsilyl-2-propene, via mesylation followed by iodide displacement.
General description
trans-3-(Trimethylsilyl)allyl alcohol is a 3-silyl allyl alcohol.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
136.4 °F - closed cup
flash_point_c
58 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Minh Pham et al.
The Journal of organic chemistry, 73(2), 741-744 (2007-12-22)
In the presence of indium metal, 3-iodo-2-[(trimethylsilyl)methyl]propene (1) reacts with sequentially added aldehydes to provide cis-2,6-disubstituted tetrahydropyrans in good yields. Evidence suggests that InI, formed upon aldehyde (R1CHO) allylation in aqueous media, acts as a promoter for the silyl-Prins reaction
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