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377171

1,2-环氧己烷

Name: 1,2-环氧己烷
Brand: ALDRICH

97%

别名:

1-己烯氧化物, 丁基环氧乙烷

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关于此项目

经验公式（希尔记法）:

C₆H₁₂O

化学文摘社编号:

1436-34-6

分子量:

100.16

UNSPSC Code:

12162002

NACRES:

NA.23

PubChem Substance ID:

24863209

EC Number:

215-864-6

Beilstein/REAXYS Number:

102568

MDL number:

MFCD00005154

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属性

Quality Level

100

assay

97%

form

liquid

impurities

<3% acetic acid

refractive index

n20/D 1.406 (lit.)

bp

118-120 °C (lit.)

density

0.831 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CCCCC1CO1

InChI

1S/C6H12O/c1-2-3-4-6-5-7-6/h6H,2-5H2,1H3

InChI key

WHNBDXQTMPYBAT-UHFFFAOYSA-N

说明

Application

聚（环氧氯丙烷-co-1, 2-环氧己烷）–一种前景良好的用于叠氮聚合物成型固化（cast-cure）的前体：讨论了采用环氧氯丙烷和1, 2-环氧己烷合成的一种共聚物，研究目的在于开发一种用于能量应用的内增塑剂（TM Klapötke, 2016)。
以小晶体合成的多级孔沸石（hierarchically porous zeolite） TS-1 及其1-己烯环氧化反应性能：该研究考察了1, 2-环氧己烷在各种化学行业用中间体制备中的催化性能（M Zhang et al., 2021）。
利用来自红球菌 ST‐10（RhSMO）的苯乙烯单加氧酶进行手性环氧烷烃的生物生产：关注了利用生物催化剂进行（S）-1,2-环氧己烷的酶法生产，重点介绍了其在手性环氧烷烃制备中的潜力（H Toda et al., 2014)。
用于增进1-己烯环氧化性能的、硅岛（Silica island）调节TS‐1的外部T位环境（external Ti‐site environment）：探索了利用TS-1 改性催化剂改善环氧化反应中1-己烯的性能（（J Yuan et al., 2023）。
采用非均相半导体材料进行1-己烯的气相光催化氧化：描述了通过气相光催化氧化进行1, 2-环氧己烷的合成，重点关注了过程的选择性和效率（EA Kamba et al., 2023）。

pictograms

GHS02,GHS07

signalword

Danger

hcodes

H225,H302,H315,H319,H335

pcodes

P210 - P233 - P240 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

59.0 °F - closed cup

flash_point_c

15 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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全球贸易项目编号

货号	GTIN
377171-100G	04061831835519
377171-25G	04061831835533