378232
六氰基钌(II)酸钾 水合物
别名:
Tetrapotassium ruthenium(2+) hexacyanide hydrate
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关于此项目
线性分子式:
K4Ru(CN)6·xH2O
化学文摘社编号:
分子量:
413.57 (anhydrous basis)
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Form:
powder
InChI
1S/6CN.4K.H2O.Ru/c6*1-2;;;;;;/h;;;;;;;;;;1H2;/q;;;;;;4*+1;;-3
SMILES string
O.[K+].[K+].[K+].[K+].N#C[Ru-3](C#N)(C#N)(C#N)(C#N)C#N
InChI key
FUVXNNWKCOQHNS-UHFFFAOYSA-N
form
powder
reaction suitability
core: potassium
Quality Level
General description
六氰基钌酸四钾盐水合物是一种晶体，常用作电镀的钌源、有机合成催化剂和纺织染料。
Application
六氰基钌酸四钾盐水合物 可作为前体，合成氰基桥联催化剂用于对硝基苯 磷酸的水解和太阳能燃料生产。 此外，它还可用于 作为起始材料，制备钌紫(ruthenium purple)薄膜， 载体为掺锡的透光铟锡氧化物(ITO)。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Synthesis, characterisation and in situ colorimetry of electrochromic Ruthenium purple thin films
Roger J Mortimer and Thomas S Varley
Dyes and Pigments, 89, 169-176 (2011)
Heterogeneous Catalysis of Lanthanoid Ions for the Hydrolysis of p-Nitrophenyl Phosphate Enhanced by Incorporation to Cyano-Bridged Heterometallic Coordination Polymers
Hiroyasu Tabe, et al.
The Journal of Physical Chemistry C, 126, 4365-4373 (2022)
Natalia Levin et al.
Inorganic chemistry, 59(12), 8272-8283 (2020-05-12)
Ruthenium 4d-to-2p X-ray emission spectroscopy (XES) was systematically explored for a series of Ru2+ and Ru3+ species. Complementary density functional theory calculations were utilized to allow for a detailed assignment of the experimental spectra. The studied complexes have a range
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