降龙涎香醚

Name: 降龙涎香醚
Brand: ALDRICH

99%

别名:

1,5,5,9-四甲基-13-氧杂三环[8.3.0.0^4,9]十三烷

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所有图片(1)

About This Item

经验公式（希尔记法）:

C₁₆H₂₈O

CAS Number:

6790-58-5

分子量:

236.39

EC 号:

229-861-2

MDL编号:

MFCD00134491

UNSPSC代码:

12352005

PubChem化学物质编号:

24863228

方案

99%

旋光性

[α]20/D −29°, c = 1 in toluene

mp

74-76 °C (lit.)

SMILES字符串

CC1(C)CCC[C@@]2(C)[C@H]1CC[C@@]3(C)OCC[C@H]23

InChI

1S/C16H28O/c1-14(2)8-5-9-15(3)12(14)6-10-16(4)13(15)7-11-17-16/h12-13H,5-11H2,1-4H3/t12-,13+,15-,16+/m0/s1

InChI key

YPZUZOLGGMJZJO-LQKXBSAESA-N

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一般描述

Ambroxide is a terpenoid, which has vast applications in the perfume industry due to its fixative property and odor. Ambergris, which was originally sourced from sperm whale, has been substituted by synthetic ambroxides.

应用

(−)-Ambroxide can be used:

To prepare (+)-sclareolide through C−H oxidation strategy.
As a substrate in C(sp³)-H alkylation/arylation studies of ethers.
As a substrate in the study of ethereal hydrocarbon hydroperoxidation using singlet O₂.