379220
降龙涎香醚
99%
别名:
1,5,5,9-四甲基-13-氧杂三环[8.3.0.04,9]十三烷
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关于此项目
经验公式（希尔记法）:
C16H28O
化学文摘社编号:
分子量:
236.39
UNSPSC Code:
12352005
PubChem Substance ID:
EC Number:
229-861-2
MDL number:
产品名称
降龙涎香醚, 99%
InChI key
YPZUZOLGGMJZJO-LQKXBSAESA-N
InChI
1S/C16H28O/c1-14(2)8-5-9-15(3)12(14)6-10-16(4)13(15)7-11-17-16/h12-13H,5-11H2,1-4H3/t12-,13+,15-,16+/m0/s1
SMILES string
CC1(C)CCC[C@@]2(C)[C@H]1CC[C@@]3(C)OCC[C@H]23
assay
99%
optical activity
[α]20/D −29°, c = 1 in toluene
mp
74-76 °C (lit.)
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Application
(−)-Ambroxide can be used:
- To prepare (+)-sclareolide through C−H oxidation strategy.
- As a substrate in C(sp3)-H alkylation/arylation studies of ethers.
- As a substrate in the study of ethereal hydrocarbon hydroperoxidation using singlet O2.
General description
Ambroxide is a terpenoid, which has vast applications in the perfume industry due to its fixative property and odor. Ambergris, which was originally sourced from sperm whale, has been substituted by synthetic ambroxides.
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Recent developments in natural product synthesis using metal-catalysed C-H bond functionalisation
McMurray L, et al.
Chemical Society Reviews, 40(4), 1885-1898 (2011)
The Combination of Benzaldehyde and Nickel-Catalyzed Photoredox C (sp3)- H Alkylation/Arylation
Zhang L, et al.
Angewandte Chemie (International Edition in English), 58(6), 1823-1827 (2019)
Enzymes for Synthetic Biology of Ambroxide-Related Diterpenoid Fragrance Compounds
Biotechnology of Isoprenoids (2015)
Singlet oxygen-mediated selective C--H bond hydroperoxidation of ethereal hydrocarbons
Sagadevan A, et al.
Nature Communications, 8(1), 1-8 (2017)
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