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经验公式(希尔记法):
C11H6N2O
化学文摘社编号:
分子量:
182.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
4,5-二氮芴-9-酮, 97%
InChI
1S/C11H6N2O/c14-11-7-3-1-5-12-9(7)10-8(11)4-2-6-13-10/h1-6H
SMILES string
O=C1c2cccnc2-c3ncccc13
InChI key
PFMTUGNLBQSHQC-UHFFFAOYSA-N
assay
97%
mp
214-217 °C (lit.)
solubility
THF: soluble(lit.)
benzene: soluble(lit.)
dichloromethane: soluble(lit.)
toluene: soluble(lit.)
functional group
ketone
Quality Level
Application
4,5-二氮芴-9-酮可通过与各种二胺、肼、1,4-苯二胺、联苯胺和 4,4′-亚甲基二苯胺缩合, 用于制备杂环配体。它可用于制备 9-重氮-4,5-二氮芴。
General description
4,5-二氮芴-9-酮是一种用于合成各种杂环化合物的杂环合成砌块,也可用作荧光探针。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Youxiang Wang et al.
Inorganic chemistry, 37(9), 2227-2234 (2001-10-24)
A series of bimetallic complexes of ruthenium(II) bridged by heterocyclic ligands formed by the condensation of 4,5-diazafluoren-9-one with various diamines, hydrazine, 1,4-phenylenediamine, benzidine, and 4,4'-methylenedianiline, results in metal centers separated by various distances. The complexes give rise to metal-to-ligand charge-transfer
4, 5-Diazafluoren-9-one from the oxidation of 1, 10-phenanthroline by permanganate.
Eckhard IF and Summers LA.
Australian Journal of Chemistry, 26(12), 2727-2728 (1973)
4, 5-Diazafluoren-9-one.
Fun HK, et al.
Acta Crystallographica Section C, Crystal Structure Communications, 51(10), 2076-2078 (1995)
4, 5-Diazafluoren-9-one.
Fun H-K, et al.
Acta Crystallographica Section C, Structural Chemistry, 51(10), 2076-2078 (1995)
Synthesis and Application of New Ru (II) Complexes for Dye-Sensitized Nanocrystalline TiO2 Solar Cells.
Seok WK, et al.
Bull. Korean Chem. Soc., 28(8), 1311-1311 (2011)
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