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379670

[1,1′-双(二苯基膦)二茂铁]二氯化钯(II)二氯甲烷络合物

greener alternative

solid

别名:

Pd(dppf)Cl2 · CH2Cl2, Pd(dppf)Cl2 · DCM, [1,1′-二(二苯基膦基)二氯化钯（1：1）

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关于此项目

经验公式（希尔记法）:
C35H30Cl4FeP2Pd
化学文摘社编号:
95464-05-4
分子量:
816.64
UNSPSC Code:
12161600
PubChem Substance ID:
24863679
NACRES:
NA.22
MDL number:
MFCD00792899
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产品名称

[1,1′-双(二苯基膦)二茂铁]二氯化钯(II)二氯甲烷络合物,

form

solid

Quality Segment

200

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

275-280 °C

greener alternative category

Aligned

SMILES string

[Fe].ClCCl.Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.CH2Cl2.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h2*1-14H;1H2;2*1H;;/q;;;;;;+2/p-2

InChI key

CWHRHCATIKFSND-UHFFFAOYSA-L

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is a widely used bidentate phosphine ligand in homogeneous catalysis. Click here for more information.

Application

钯催化交叉偶联反应应用指南

Analysis Note

催化剂，用于芳基卤化物和双(频哪醇合)二硼 (473294) 的硼化反应，以及芳基硼酯衍生物和芳基卤化物偶联生成联芳基化合物的反应。也可用于 CO 插入反应合成内酰胺以及芳基卤化物和醇的分子内偶联反应合成中环芳基醚。

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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