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379891

高碘酸

Name: 高碘酸
Brand: ALDRICH

99.999% trace metals basis

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关于此项目

经验公式（希尔记法）:

H₅IO₆

化学文摘社编号:

10450-60-9

分子量:

227.94

NACRES:

NA.22

PubChem Substance ID:

24863698

UNSPSC Code:

12352301

EC Number:

233-937-0

MDL number:

MFCD00011344

Assay:

99.999% trace metals basis

Form:

crystals

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属性

Quality Level

200

assay

99.999% trace metals basis

form

crystals

reaction suitability

reagent type: oxidant

mp

122 °C (lit.)

solubility

water: soluble

SMILES string

OI(O)(O)(O)(O)=O

InChI

1S/H5IO6/c2-1(3,4,5,6)7/h(H5,2,3,4,5,6,7)

InChI key

TWLXDPFBEPBAQB-UHFFFAOYSA-N

说明

General description

Periodic acid (H₅IO₆) is an oxoacid of iodine. It is commonly used as an oxidizing agent in organic synthesis for the preparation of useful chemical intermediates. Periodic acid is also used in oxidative cleavage reactions.

Application

Periodic acid can be used as a reagent:

In the oxidative cleavage of 1,2 diols and epoxides to ketones or aldehydes.
For the oxidation of alcohols to ketones or aldehydes in the presence of pyridinium chlorochromate as a catalyst.
For the oxidation of sulfides to sulfones using chromium(VI) oxide catalyst.
For the oxidation of naphthalenes and anthracene to quinones using chromium(VI) oxide catalyst.
In the synthesis of polyaniline (Pani) by chemical polymerization.
N-nitrosation of secondary amines using various heterogeneous catalysts in the presence of Na₂NO₃.
In combination with sodium bisulfate for the preparation iodohydrin substituents by the addition of I-OH to alkenes.