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Merck
CN

380210

1,1′-偶氮双(环己烷甲腈)

98%

别名:

1,1′-偶氮(氰基环己烷), ACHN, VAZO 催化剂 88 自由基源

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关于此项目

线性分子式:
NCC6H10N=NC6H10CN
化学文摘社编号:
分子量:
244.34
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
218-254-8
Beilstein/REAXYS Number:
960744
MDL number:
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Quality Level

assay

98%

form

solid

mp

114-118 °C (lit.)

storage temp.

2-8°C

SMILES string

N#CC1(CCCCC1)\N=N\C2(CCCCC2)C#N

InChI

1S/C14H20N4/c15-11-13(7-3-1-4-8-13)17-18-14(12-16)9-5-2-6-10-14/h1-10H2/b18-17+

InChI key

KYIKRXIYLAGAKQ-ISLYRVAYSA-N

General description

1,1′-偶氮双(环己烷甲腈)(AHCN)是对热稳定的引发剂,可用于自由基聚合。 可溶于甲醇、二甲基甲酰胺(DMF)等多种溶剂。

Application

作为比 AIBN 更加有效的自由基引发剂,已被用于引发主要的自由基反应。


pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Self-react. D - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

5.2 - Organic peroxides and self-reacting hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

监管及禁止进口产品

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历史批次信息供参考:

分析证书(COA)

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实验方案

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

商品

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

RAFT(可逆加成断裂链转移)聚合是一种可逆的去活化自由基聚合(RDRP),是给自由基聚合赋予活性的通用方法之一。


1, 11 AZOBIS (CYCLOHEXANECARBONITRILE) INITIATED COPOLYMERIZATION OF ACRYLONITRILE COPOLYMERS AND THEIR CHARACTERIZATION
Sridevi S, et al.
Chem, 2(5), 61-61 (2009)
The Journal of Organic Chemistry, 52, 2958-2958 (1987)
Youfeng Yue et al.
Nature communications, 9(1), 3234-3234 (2018-08-15)
Energy conversion of light into mechanical work is of fundamental interest in applications. In particular, diligent molecular design on nanoscale, in order to achieve efficient photomechanical effects on macroscopic scale, has become one of the most interesting study topics. Here



全球贸易项目编号

货号GTIN
380210-100G04061831960365
380210-25G04061831960389