380474
2-羟乙基二硫化物
technical grade
别名:
2,2′-二硫二乙醇, 双(2-羟乙基)二硫代
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线性分子式:
HOCH2CH2SSCH2CH2OH
化学文摘社编号:
分子量:
154.25
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
217-576-6
Beilstein/REAXYS Number:
1735851
MDL number:
产品名称
2-羟乙基二硫化物, technical grade
InChI key
KYNFOMQIXZUKRK-UHFFFAOYSA-N
InChI
1S/C4H10O2S2/c5-1-3-7-8-4-2-6/h5-6H,1-4H2
SMILES string
OCCSSCCO
grade
technical grade
form
liquid
refractive index
n20/D 1.57 (lit.)
bp
158-163 °C/3.5 mmHg (lit.)
mp
25-27 °C (lit.)
density
1.261 g/mL at 25 °C (lit.)
Quality Level
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Application
双(2-羟乙基)二硫化物可用作：
- 扩链剂，用于制备水性自修复聚氨酯，作为皮革涂饰。
- 前体，用于合成多功能引发剂，用于苯乙烯经原子转移自由基聚合为星形聚苯乙烯。
- 起始材料，用于制备二硫化物支化剂。该支化剂可用于合成高度分支的聚甲基丙烯酸羟丙酯。
General description
2-羟乙基二硫化物(HEDS)是一种有机硫化合物，属于二烷基二硫化物类，其中的两个羟乙基之间存在-S-S- 键。在材料科学中，HEDS可作为前体用于在金表面形成自组装单层（SAM），应用包括防腐蚀、润滑和传感器。此外，2-羟乙基二硫化物也用作有机合成中的还原剂，以及橡胶化合物生产中的交联剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
233.6 °F - closed cup
flash_point_c
112 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
J E Brotherton et al.
Physiological chemistry and physics, 12(6), 483-495 (1980-01-01)
Incubation of horse liver aldehyde dehydrogenase (aldehyde:NAD oxidoreductase, EC 1.2.1.3) with 2-hydroxyethyl disulfide formed mixed-disulfides between protein sulfhydryl groups and beta-mercaptoethanol. Reduction of aldehyde dehydrogenase activity may be associated with formation of one, or at most two, mixed-disulfides per dehydrogenase
Cristina Lamberti et al.
Electrophoresis, 28(10), 1633-1638 (2007-05-12)
Despite the large number of papers dealing with bacterial proteomes, very few include information about proteins with alkaline pI's, because of the limits inherent in 2-DE technology. Nonetheless, analyses of in silico proteomes of many prokaryotes show a bimodal distribution
P C Hiestand et al.
International journal of immunopharmacology, 7(1), 129-140 (1985-01-01)
HEDS (2-hydroxyethyl disulfide) and structurally related compounds were found to affect lymphocyte proliferation and functions in vitro. HEDS, and ADA 202-718 (ethylene-2-2'-bis(dithio)bis(ethanol], were shown to stimulate the proliferation of murine spleen cells. The growth of populations of murine T-cells (thymocytes)
Rakesh Kumar et al.
Biomacromolecules, 9(9), 2430-2437 (2008-08-01)
Biodegradable soy protein isolate (SPI), containing 2,2-diphenyl-2-hydroxyethanoic acid, films (SB) were successfully prepared with bis-(2-hydroxyethyl)sulfide as a plasticizer by compression molding at 155 degrees C and 15 MPa. By immersing the SB in distilled water for 26 h, we prepared
Nikola Mesecke et al.
Biochemistry, 47(5), 1452-1463 (2008-01-04)
Two novel monothiol glutaredoxins from yeast (ScGrx6 and ScGrx7) were identified and analyzed in vitro. Both proteins are highly suited to study structure-function relationships of glutaredoxin subclasses because they differ from all monothiol glutaredoxins investigated so far and share features
商品
Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.
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