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Merck
CN

381586

1-正丁氨基甲酰-2-苯并咪唑氨基甲酸甲酯

95%

别名:

NSC 263489, 苯菌灵

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关于此项目

经验公式(希尔记法):
C14H18N4O3
化学文摘社编号:
分子量:
290.32
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
241-775-7
Beilstein/REAXYS Number:
825455
MDL number:
Assay:
95%
Form:
solid
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InChI key

RIOXQFHNBCKOKP-UHFFFAOYSA-N

InChI

1S/C14H18N4O3/c1-3-4-9-15-13(19)18-11-8-6-5-7-10(11)16-12(18)17-14(20)21-2/h5-8H,3-4,9H2,1-2H3,(H,15,19)(H,16,17,20)

SMILES string

CCCCNC(=O)n1c(NC(=O)OC)nc2ccccc12

assay

95%

form

solid

mp

>300 °C (lit.)

functional group

amine

Quality Level

General description

1-(丁基氨基甲酰基)-2-苯并咪唑氨基甲酸甲酯(苯菌灵)广泛用于治疗农业中的各种真菌疾病。据报道,它是杜邦苯酯杀菌剂的活性成分。采用分光光度法研究了苯基在各种有机溶剂中的降解动力学。据报道, N,N′-二丁基脲(DBU)是苯菌灵的主要代谢产物。

Application

1-(丁基氨基甲酰基)-2-苯并咪唑氨基甲酸甲酯可作为水、沉积物和生物样品中苯并咪酯含量 HPLC 测定的标准试剂。

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Muta. 1B - Repr. 1B - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品
农药列管产品
此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Jayne Aiken et al.
Cytoskeleton (Hoboken, N.J.), 77(3-4), 40-54 (2019-10-02)
The neuronal cytoskeleton performs incredible feats during nervous system development. Extension of neuronal processes, migration, and synapse formation rely on the proper regulation of microtubules. Mutations that disrupt the primary α-tubulin expressed during brain development, TUBA1A, are associated with a
Analysis of benomyl by liquid chromatography/time-of-flight mass spectrometer and its occurrence in the environment.
Seo YC, et al.
Bull. Korean Chem. Soc., 23(3), 432-436 (2002)
Kamlesh Gupta et al.
Biochemistry, 43(21), 6645-6655 (2004-05-26)
The antifungal agent benomyl [methyl-1-(butylcarbamoyl)-2-benzimidazolecarbamate] is used throughout the world against a wide range of agricultural fungal diseases. In this paper, we investigated the interaction of benomyl with mammalian brain tubulin and microtubules. Using the hydrophobic fluorescent probe 1-anilinonaphthalene-8-sulfonic acid
Stephen A Sassman et al.
Journal of agricultural and food chemistry, 52(4), 747-754 (2004-02-19)
N,N'-Dibutylurea (DBU) is a breakdown product of benomyl [methyl 1-(butylcarbamoyl)-2-benzimidazole carbamate], the active ingredient in Benlate fungicides, and has been proposed as one cause for crop damage that growers claim to have occurred from the use of Benlate 50 DF
Kinetic study of reversible conversion of methyl 1-(butylcarbamoyl)-2-benzimidazolecarbamate (benomyl) to methyl 2-benzimidazolecarbamate (MBC) and n-butyl isocyanate (BIC) in organic solvents.
Chiba M and Cherniak EA.
Journal of Agricultural and Food Chemistry, 26(3), 573-576 (1978)

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