382043
苄基-3-溴丙醚
98%
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关于此项目
线性分子式:
C6H5CH2O(CH2)3Br
化学文摘社编号:
分子量:
229.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
98%
Form:
liquid
InChI
1S/C10H13BrO/c11-7-4-8-12-9-10-5-2-1-3-6-10/h1-3,5-6H,4,7-9H2
SMILES string
BrCCCOCc1ccccc1
InChI key
PSUXTZLDBVEZTD-UHFFFAOYSA-N
assay
98%
form
liquid
refractive index
n20/D 1.531 (lit.)
bp
130-132 °C/8 mmHg (lit.)
density
1.298 g/mL at 25 °C (lit.)
functional group
bromo, ether, phenyl
Quality Level
General description
苄基-3-溴丙烷醚是一种醚。
Application
苄基-3-溴丙烷醚可用于以下研究：
- 制备(2S,3S)-1-[(三异丙基甲硅烷基)氧基] -7-(苄氧基)-2,3-(异亚丙基二氧基)-4(Z)-庚烯。
- 制备5-(3-苄氧基丙氧基)补骨脂素（PAP-7）。
- zincophorin 和(+)-鱼腥藻毒素的全合成。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Magali Defosseux et al.
The Journal of organic chemistry, 69(14), 4626-4647 (2004-07-03)
A total synthesis of the naturally occurring ionophore zincophorin has been realized. The route features an intramolecular oxymercuration of a cyclopropanemethanol and a Carroll-Claisen rearrangement for the respective elaboration of the C1-C12 and C13-C25 subunits, which have been assembled by
Synthesis of natural and modified trapoxins, useful reagents for exploring histone deacetylase function.
Taunton J, et al.
Journal of the American Chemical Society, 118(43), 10412-10422 (1996)
Alexander Schmitz et al.
Molecular pharmacology, 68(5), 1254-1270 (2005-08-16)
The lymphocyte K+ channel Kv1.3 constitutes an attractive pharmacological target for the selective suppression of terminally differentiated effector memory T (TEM) cells in T cell-mediated autoimmune diseases, such as multiple sclerosis and type 1 diabetes. Unfortunately, none of the existing
Tetrahedron Letters, 45, 4397-4399 (2004)
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