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382655

2-羟甲基-12-冠-4

Name: 2-羟甲基-12-冠-4
Brand: ALDRICH

95%

别名:

(12-冠-4)-2-甲醇, 1,4,7,10-四氧环十二烷-2-甲醇

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关于此项目

经验公式（希尔记法）:

C₉H₁₈O₅

化学文摘社编号:

75507-26-5

分子量:

206.24

UNSPSC Code:

12352005

NACRES:

NA.22

PubChem Substance ID:

24863907

EC Number:

278-224-5

Beilstein/REAXYS Number:

4661968

MDL number:

MFCD00067524

Assay:

95%

Form:

liquid

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属性

assay

95%

form

liquid

reaction suitability

core: crown ether

refractive index

n20/D 1.480 (lit.)

bp

115 °C/0.04 mmHg (lit.)

density

1.192 g/mL at 25 °C (lit.)

functional group

ether, hydroxyl

SMILES string

OCC1COCCOCCOCCO1

InChI

1S/C9H18O5/c10-7-9-8-13-4-3-11-1-2-12-5-6-14-9/h9-10H,1-8H2

InChI key

NJIPEIQHUNDGPY-UHFFFAOYSA-N

说明

Application

2-Hydroxymethyl-12-crown-4 can be used:

To prepare an ester of lasalocid with crown ether to study its complex formation with monovalent cations.
To prepare hydrogel adsorbents for potential usage in the recovery of lithium-ions from seawater.
As a starting material in the synthesis of metal-free phthalocyanines and metallophthalocyanines.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Crown Ethers and Cryptands for Advanced Applications

Crown ethers and cryptands, complexing agents able to selectively bind metal cations, are vital for diverse synthesis and analytical applications.

Hydrogel adsorbents of poly (N-isopropylacrylamide-co-methacryloyloxymethyl-12-crown-4) for Li+ recovery prepared by droplet microfluidics

Kim YS, et al.

Royal Society of Chemistry Advances, 5(14), 10656-10661 (2015)

The synthesis, using microwave irradiation and characterization of novel, organosoluble metal-free and metallophthalocyanines substituted with flexible crown ether moieties

Biyikliouglu Z and Kantekin H

Dyes and Pigments, 80(1), 17-21 (2009)

NMR, FT-IR and ESI-MS study of new lasalocid ester with 2-(hydroxymethyl)-12-crown-4 and its complexes with monovalent cations

Pankiewicz R, et al.

Journal of Molecular Structure, 749(1-3), 128-137 (2005)

全球贸易项目编号

货号	GTIN
382655-1G	04061838111173