表单
liquid
浓度
70 wt. % in toluene
折射率
n20/D 1.456
密度
0.963 g/mL at 25 °C
官能团
alkyl halide
chloro
储存温度
2-8°C
SMILES字符串
ClCC#C
InChI
1S/C3H3Cl/c1-2-3-4/h1H,3H2
InChI key
LJZPPWWHKPGCHS-UHFFFAOYSA-N
一般描述
Product is the 70wt.% solution of propargyl chloride in toluene. Propargyl chloride is a propargyl halide. Its trimethylsilylation reaction has been reported. Liquid-phase Raman spectra, and vapor-phase and solution-phase infrared spectra of propargyl chloride has been studied at 100-3400cm-1 and 300-3800cm-1, respectively. It participates in the addition reaction with acyclic 1,3-dienes (at -78°C) in the presence of zinc chloride.
应用
Propargyl chloride may be used as propargylating agent in the preparation of arabinogalactan propargyl ethers with degree of substitution up to 1.8. It may be used for the in situ preparation of propargyltrichlorosilane and allenyltrichlorosilane, required for the synthesis of optically active allenic and homopropargylic alcohols.
Propargyl chloride solution may be used for the enantioselective synthesis of enantiomerically enriched homopropargyl alcohols.
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
靶器官
Central nervous system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
66.2 °F
闪点(°C)
19 °C
法规信息
新产品
此项目有
Chemo-and enantioselective catalytic addition of propargyl chloride to aldehydes promoted by [Cr (Salen)] complexes.
Bandini M, et al.
Tetrahedron Asymmetry, 12(7), 1063-1069 (2001)
The vibrational spectra and vibrational assignments of the propargyl halides.
Evans JC and Nyquist RA.
Spectrochimica Acta Part A: Molecular Spectroscopy, 19(7), 1153-1163 (1963)
Trimethylsilylation of Propargyl Chloride and Propargyl Bromide.
Verkruijsse HD and Brandsma L.
Synthetic Communications, 20(21), 3375-3378 (1990)
Zinc chloride catalyzed addition reactions of propargyl chlorides with acyclic 1, 3-dienes.
Mayr H and Klein H.
The Journal of Organic Chemistry, 46(20), 4097-4100 (1981)
Selective synthesis of optically active allenic and homopropargylic alcohols from propargyl chloride.
Nakajima M, et al.
Tetrahedron Asymmetry, 12(22), 2449-2452 (2002)
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