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表单
liquid
浓度
70 wt. % in toluene
折射率
n20/D 1.456
密度
0.963 g/mL at 25 °C
官能团
alkyl halide
chloro
储存温度
2-8°C
SMILES字符串
ClCC#C
InChI
1S/C3H3Cl/c1-2-3-4/h1H,3H2
InChI key
LJZPPWWHKPGCHS-UHFFFAOYSA-N
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此商品 | VBP00035 | VBP00049 | PH018803 |
---|---|---|---|
form solid | form solid | form solid | form solid |
一般描述
Product is the 70wt.% solution of propargyl chloride in toluene. Propargyl chloride is a propargyl halide. Its trimethylsilylation reaction has been reported.[1] Liquid-phase Raman spectra, and vapor-phase and solution-phase infrared spectra of propargyl chloride has been studied at 100-3400cm-1 and 300-3800cm-1, respectively.[2] It participates in the addition reaction with acyclic 1,3-dienes (at -78°C) in the presence of zinc chloride.[3]
应用
Propargyl chloride may be used as propargylating agent in the preparation of arabinogalactan propargyl ethers with degree of substitution up to 1.8.[4] It may be used for the in situ preparation of propargyltrichlorosilane and allenyltrichlorosilane, required for the synthesis of optically active allenic and homopropargylic alcohols.[5]
Propargyl chloride solution may be used for the enantioselective synthesis of enantiomerically enriched homopropargyl alcohols.[6]
警示用语:
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
靶器官
Central nervous system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
66.2 °F
闪点(°C)
19 °C
法规信息
新产品
Nenad Manevski et al.
Drug metabolism and disposition: the biological fate of chemicals, 43(1), 126-139 (2014-10-24)
Although skin is the largest organ of the human body, cutaneous drug metabolism is often overlooked, and existing experimental models are insufficiently validated. This proof-of-concept study investigated phase II biotransformation of 11 test substrates in fresh full-thickness human skin explants
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