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384321

Sigma-Aldrich

炔丙氯 溶液

70 wt. % in toluene

别名:

3-氯丙炔

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200 MG
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200 MG
¥3,302.56

About This Item

线性分子式:
HC≡CCH2Cl
CAS Number:
分子量:
74.51
Beilstein:
506005
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

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表单

liquid

浓度

70 wt. % in toluene

折射率

n20/D 1.456

密度

0.963 g/mL at 25 °C

官能团

alkyl halide
chloro

储存温度

2-8°C

SMILES字符串

ClCC#C

InChI

1S/C3H3Cl/c1-2-3-4/h1H,3H2

InChI key

LJZPPWWHKPGCHS-UHFFFAOYSA-N

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VBP00035VBP00049PH018803
form

solid

form

solid

form

solid

form

solid

一般描述

Product is the 70wt.% solution of propargyl chloride in toluene. Propargyl chloride is a propargyl halide. Its trimethylsilylation reaction has been reported.[1] Liquid-phase Raman spectra, and vapor-phase and solution-phase infrared spectra of propargyl chloride has been studied at 100-3400cm-1 and 300-3800cm-1, respectively.[2] It participates in the addition reaction with acyclic 1,3-dienes (at -78°C) in the presence of zinc chloride.[3]

应用

Propargyl chloride may be used as propargylating agent in the preparation of arabinogalactan propargyl ethers with degree of substitution up to 1.8.[4] It may be used for the in situ preparation of propargyltrichlorosilane and allenyltrichlorosilane, required for the synthesis of optically active allenic and homopropargylic alcohols.[5]
Propargyl chloride solution may be used for the enantioselective synthesis of enantiomerically enriched homopropargyl alcohols.[6]

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3

靶器官

Central nervous system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

66.2 °F

闪点(°C)

19 °C

法规信息

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    Nenad Manevski et al.
    Drug metabolism and disposition: the biological fate of chemicals, 43(1), 126-139 (2014-10-24)
    Although skin is the largest organ of the human body, cutaneous drug metabolism is often overlooked, and existing experimental models are insufficiently validated. This proof-of-concept study investigated phase II biotransformation of 11 test substrates in fresh full-thickness human skin explants

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