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Merck
CN

390380

4-乙酰氨-2,2,6,6-四甲基哌啶-1-氧,自由基

97%

别名:

4-乙酰氨-2,2,6,6-四甲基哌啶-1-氧

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关于此项目

经验公式(希尔记法):
C11H21N2O2
化学文摘社编号:
分子量:
213.30
UNSPSC Code:
12352000
NACRES:
NA.22
PubChem Substance ID:
EC Number:
423-840-3
Beilstein/REAXYS Number:
3546225
MDL number:
Assay:
97%
Form:
powder
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InChI key

UXBLSWOMIHTQPH-UHFFFAOYSA-N

InChI

1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)

SMILES string

CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1

assay

97%

form

powder

mp

143-145 °C (lit.)

Quality Level

Application

在 TsOH 存在的条件下将醇氧化为羰基化合物。

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

存储类别

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

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The Journal of Organic Chemistry, 56, 6110-6110 (1991)
Lenka Vítková et al.
Polymers, 11(9) (2019-09-22)
In the current study, we present methods of sodium hyaluronate, also denoted as hyaluronan (HA), nanofiber fabrication using a direct-current (DC) electric field. HA was spun in combination with poly(vinyl alcohol) (PVA) and polyethylene oxide (PEO) and as a pure
Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes.
Yin W, et al.
Advanced Synthesis & Catalysis, 352(1, 113-118 (2010)
D Metodiewa et al.
Biochemistry and molecular biology international, 40(6), 1211-1219 (1996-12-01)
Two novel 2,2,6,6-tetramethylpiperidine derivatives (Tempace and Troxyl) were synthesized and their capacity to act as scavengers of superoxide, inhibitors of iron and ascorbate-driven Fenton reaction and radioprotectors was tested. The possibility for one-electron oxidation of novel compounds by heme-ferryl species
D Metodiewa et al.
Anticancer research, 19(2A), 1255-1260 (1999-06-16)
Since flavanone oximes derivatives (ethers) have been shown to modulate the growth of Yoshida Sarcoma cells in vivo and to induce apoptosis, the effects of these substances on immortalized cell lines growth were examined. Cell viability and sensitivity to investigated

商品

TEMPO(2,2,6,6-四甲基哌啶氧基或2,2,6,6-四甲基哌啶1-氧基)及其衍生物在有机氧化反应催化剂中可以作为稳定的硝酰基使用。TEMPO由Lebedev和Kazarnovskii于1960年发现,其具有的稳定自由基性质得益于其庞大的取代基团阻碍了自由基与其他分子之间发生反应。

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