391638
二甲基氯化磷胺
97%
别名:
(Dichlorophosphanyl)dimethylamine, (Dimethylamino)dichlorophosphine, Dichloro(dimethylamido)phosphorus, Dichloro(dimethylamino)phosphine, Dichloro-N,N-dimethylaminophosphine, N,N-Dimethylphosphoramidous dichloride
质量水平
方案
97%
表单
liquid
折射率
n20/D 1.505 (lit.)
沸点
150 °C (lit.)
密度
1.271 g/mL at 25 °C (lit.)
官能团
amine
储存温度
2-8°C
SMILES字符串
CN(C)P(Cl)Cl
InChI
1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3
InChI key
XPWWDZRSNFSLRQ-UHFFFAOYSA-N
一般描述
Dimethylphosphoramidous dichloride (dimethylaminodichlorophosphine) is a phosphorus chloride derivative. It exists in two stable isomers, a gauche-conformer with C1 symmetry and anti-conformer with Cs symmetry. Its synthesis has been reported. Molecular conformation has been investigated through correlation between the 35Cl NQR frequencies and charge on the chlorine atoms. Its vibrational spectra has been studied. Its reaction with SO2 has been investigated. It participates in the synthesis of [(dimethylamino)phosphoryl] bis(difluoromethylene)phosphonate.
应用
Dimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following:
- N,N-dimethylamidotetrachlorophosphorane
- O-propylchloroformimino-N,N-dimethylamidochlorophosphate
- 1,3-bisarylsulphonyl-1,3,2,4-diazadiphosphetidines
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
-9.4 °F - closed cup
闪点(°C)
-23 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Equilibrium conformation of dimethylaminodichlorophosphine molecule: the use of the results of quantum-chemical calculations and spectroscopic measurements in the analysis of gas-phase electron diffraction data.
Khaikin LS, et al.
Russian Chemical Bulletin, 50(9), 1550-1562 (2001)
Vibrational spectra and structure of dimethylaminodichlorophosphine.
Durig JR and Casper JM
The Journal of Physical Chemistry, 75(25), 3837-3843 (1971)
Organophosphorus chemistry. Part XIV. Reaction of phosphorodiamidous chlorides with sulphonamides: a new route to diazadiphosphetidines.
Bowden FL, et al.
Journal of the Chemical Society. Perkin Transactions 1, 516-520 (1973)
Dimethylaminodimethylphosphine1.
Burg AB and Slota Jr PJ.
Journal of the American Chemical Society, 80(5), 1107-1109 (1958)
G K Surya Prakash et al.
Proceedings of the National Academy of Sciences of the United States of America, 107(36), 15693-15698 (2010-08-21)
It is difficult to overestimate the importance of nucleoside triphosphates in cellular chemistry: They are the building blocks for DNA and RNA and important sources of energy. Modifications of biologically important organic molecules with fluorine are of great interest to
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持