Merck
CN
所有图片(1)

文件

安全信息

391638

Sigma-Aldrich

二甲基氯化磷胺

97%

登录查看公司和协议定价
所有图片(1)
别名:
(Dichlorophosphanyl)dimethylamine, (Dimethylamino)dichlorophosphine, Dichloro(dimethylamido)phosphorus, Dichloro(dimethylamino)phosphine, Dichloro-N,N-dimethylaminophosphine, N,N-Dimethylphosphoramidous dichloride
线性分子式:
(CH3)2NPCl2
CAS号:
683-85-2
分子量:
145.96
MDL编号:
MFCD00013613
PubChem化学物质编号:
24864392
NACRES:
NA.22

质量水平

100

检测方案

97%

形式

liquid

折射率

n20/D 1.505 (lit.)

bp

150 °C (lit.)

密度

1.271 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

CN(C)P(Cl)Cl

InChI

1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3

InChI key

XPWWDZRSNFSLRQ-UHFFFAOYSA-N

一般描述

Dimethylphosphoramidous dichloride (dimethylaminodichlorophosphine) is a phosphorus chloride derivative. It exists in two stable isomers, a gauche-conformer with C1 symmetry and anti-conformer with Cs symmetry. Its synthesis has been reported. Molecular conformation has been investigated through correlation between the 35Cl NQR frequencies and charge on the chlorine atoms. Its vibrational spectra has been studied. Its reaction with SO2 has been investigated. It participates in the synthesis of [(dimethylamino)phosphoryl] bis(difluoromethylene)phosphonate.

应用

Dimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following:
  • N,N-dimethylamidotetrachlorophosphorane
  • O-propylchloroformimino-N,N-dimethylamidochlorophosphate
  • 1,3-bisarylsulphonyl-1,3,2,4-diazadiphosphetidines

象形图

FlameCorrosion
GHS02,GHS05

警示用语：

Danger

危险声明

H225 - H314

危险分类

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

补充剂危害

EUH014

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

-9.4 °F - closed cup

闪点(°C)

-23 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ （Lot或Batch）字后找到。

已有该产品？

为方便起见，与您过往购买产品相关的文件已保存在文档库中。

访问文档库

难以找到您所需的产品或批次号码？

在网站页面上，产品编号会附带包装尺寸/数量一起显示（例如：T1503-25G）。请确保 在“产品编号”字段中仅输入产品编号 (示例: T1503).

示例

T1503
货号
-
25G
包装规格/数量

其它示例：

705578-5MG-PW

PL860-CGA/SHF-1EA

MMYOMAG-74K-13

1000309185

输入内容 1.000309185)

遇到问题？欢迎随时联系我们技术服务 寻求帮助

批号可以在产品标签上"批“ （Lot或Batch）字后面找到。

Aldrich 产品

  • 如果您查询到的批号为 TO09019TO 等，请输入去除前两位字母的批号：09019TO。

  • 如果您查询到的批号含有填充代码（例如05427ES-021），请输入去除填充代码-021的批号：05427ES。

  • 如果您查询到的批号含有填充代码（例如 STBB0728K9），请输入去除填充代码K9的批号：STBB0728。

未找到您寻找的产品？

部分情况下，可能未在线提供COA。如果搜索不到COA，可在线索取。

索取COA

G K Surya Prakash et al.
Proceedings of the National Academy of Sciences of the United States of America, 107(36), 15693-15698 (2010-08-21)
It is difficult to overestimate the importance of nucleoside triphosphates in cellular chemistry: They are the building blocks for DNA and RNA and important sources of energy. Modifications of biologically important organic molecules with fluorine are of great interest to
Reaction of 1, 1-dichloro-1-nitrosobutane with N, N-dimethylamidodichlorophosphite.
Sokolov VB, et al.
Bulletin of the Academy of Sciences of the USSR, Division of chemical science, 38(6), 1296-1298 (1989)
35Cl NQR spectra of phosphorus chlorides and their molecular conformations in crystals. Part 1. Phosphorus (III) chlorides RPCl2.
Kozlov ES, et al.
Journal of Molecular Structure, 550, 167-175 (2000)
Reactions of sulfur dioxide with aminophosphines.
Light RW and Paine RT.
Phosph. Sulfur Relat. Elem., 8(3), 255-258 (1980)
Dimethylaminodimethylphosphine1.
Burg AB and Slota Jr PJ.
Journal of the American Chemical Society, 80(5), 1107-1109 (1958)
查看所有相关文献

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门