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Merck
CN

392340

玫瑰红酸二钾盐

technical grade, 85%

别名:

5,6-二羟基-5-环己烯-1,2,3,4-四酮 二钾盐, 玫棕酸 钾盐

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关于此项目

线性分子式:
C6O6K2
化学文摘社编号:
分子量:
246.26
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
235-881-2
MDL number:
Assay:
85%
Form:
powder
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InChI key

NEWIILAQDSMNML-UHFFFAOYSA-L

InChI

1S/C6H2O6.2K/c7-1-2(8)4(10)6(12)5(11)3(1)9;;/h7-8H;;/q;2*+1/p-2

SMILES string

[K+].[K+].[O-]C1=C([O-])C(=O)C(=O)C(=O)C1=O

grade

technical grade

assay

85%

form

powder

mp

>300 °C (lit.)

General description

Potassium rhodizonate (3,4,5,6-Tetraoxocyclohexene-1,2-diol dipotassium salt, Rhodizonic acid potassium salt), a benzoquinone derivative, is the potassium salt of rhodizonic acid. Its crystalline structure has been reported and it exhibits space group Fddd. Rhodizonate dianion undergoes various thermal and photochemical reactions with various oxidizing reagents in aqueous solution.

Application

Potassium rhodizonate is suitable reagent for the preparation of staining solution used in the rhodizonate test for the detection of lead. It is suitable reagent used in the preparation of barium, thallium, ammonium and silver salts rhodizonic acid by metathesis in aqueous solution.
It may be used in the following studies:
  • To cocrystallize plutonium and radium from urine in the plutonium and radium assay of urine.
  • As a dye in the spectrophotometric determination of sulfate ion.
  • To determine the acid dissociation constants of rhodizonic acid by pH potentiometric titration of potassium rhodizonate with standardized HCl.
  • As a staining agent for plagioclase in the petrographic study.

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Dipotassium rhodizonate.
Cowan JA and Howard JAK.
Acta Crystallographica Section E, Structure Reports Online, 60(4), 511-513 (2004)
Harun Tugcu et al.
The American journal of forensic medicine and pathology, 27(4), 296-299 (2006-11-30)
It is important to investigate the clothing, as well as the body, to determine the range of fire of entry wounds in firearm injuries. Clothing can affect the amount of gunshot residues (GSR) reaching the body and their distribution. The
W Marty et al.
International journal of legal medicine, 116(1), 1-4 (2002-04-02)
The histological staining technique using rhodizonate is also effective for the determination of the firing distance by examining the distribution and intensity of the staining reaction. The differentiation between absolute close-range shots and long-range shots is generally possible without any
Fatma Gorbel et al.
Comptes rendus biologies, 325(9), 927-940 (2002-12-17)
This study deals with the impact of chronic exposure to lead on male and female fertility in rats. Male and female rats (3 months old) were fed on commercial tablets (SICO, Sfax). For drinking, some rats were given distilled water
Analysis of sulfate in complex carbohydrates.
L J Silvestri et al.
Analytical biochemistry, 123(2), 303-309 (1982-07-01)

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