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Merck
CN

392340

Sigma-Aldrich

玫瑰红酸二钾盐

technical grade, 85%

别名:

5,6-二羟基-5-环己烯-1,2,3,4-四酮 二钾盐, 玫棕酸 钾盐

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线性分子式:
C6O6K2
化学文摘社编号:
分子量:
246.26
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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等级

technical grade

方案

85%

表单

powder

mp

>300 °C (lit.)

SMILES字符串

[K+].[K+].[O-]C1=C([O-])C(=O)C(=O)C(=O)C1=O

InChI

1S/C6H2O6.2K/c7-1-2(8)4(10)6(12)5(11)3(1)9;;/h7-8H;;/q;2*+1/p-2

InChI key

NEWIILAQDSMNML-UHFFFAOYSA-L

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一般描述

Potassium rhodizonate (3,4,5,6-Tetraoxocyclohexene-1,2-diol dipotassium salt, Rhodizonic acid potassium salt), a benzoquinone derivative, is the potassium salt of rhodizonic acid. Its crystalline structure has been reported and it exhibits space group Fddd. Rhodizonate dianion undergoes various thermal and photochemical reactions with various oxidizing reagents in aqueous solution.

应用

Potassium rhodizonate is suitable reagent for the preparation of staining solution used in the rhodizonate test for the detection of lead. It is suitable reagent used in the preparation of barium, thallium, ammonium and silver salts rhodizonic acid by metathesis in aqueous solution.
It may be used in the following studies:
  • To cocrystallize plutonium and radium from urine in the plutonium and radium assay of urine.
  • As a dye in the spectrophotometric determination of sulfate ion.
  • To determine the acid dissociation constants of rhodizonic acid by pH potentiometric titration of potassium rhodizonate with standardized HCl.
  • As a staining agent for plagioclase in the petrographic study.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Harun Tugcu et al.
The American journal of forensic medicine and pathology, 27(4), 296-299 (2006-11-30)
It is important to investigate the clothing, as well as the body, to determine the range of fire of entry wounds in firearm injuries. Clothing can affect the amount of gunshot residues (GSR) reaching the body and their distribution. The
W Marty et al.
International journal of legal medicine, 116(1), 1-4 (2002-04-02)
The histological staining technique using rhodizonate is also effective for the determination of the firing distance by examining the distribution and intensity of the staining reaction. The differentiation between absolute close-range shots and long-range shots is generally possible without any
Analysis of sulfate in complex carbohydrates.
L J Silvestri et al.
Analytical biochemistry, 123(2), 303-309 (1982-07-01)
Dipotassium rhodizonate.
Cowan JA and Howard JAK.
Acta Crystallographica Section E, Structure Reports Online, 60(4), 511-513 (2004)
A spectrophotometric determination of sulfate ion and its application in studies of substrate purity and of aryl sulfatase A kinetics.
A Waheed et al.
Analytical biochemistry, 89(2), 550-560 (1978-09-01)

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