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392529

4-甲氧基-1-茚酮

Name: 4-甲氧基-1-茚酮
Brand: ALDRICH

99%

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关于此项目

经验公式（希尔记法）:

C₁₀H₁₀O₂

化学文摘社编号:

13336-31-7

分子量:

162.19

NACRES:

NA.22

PubChem Substance ID:

24864462

UNSPSC Code:

12352100

MDL number:

MFCD00077816

Assay:

99%

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属性

Quality Level

100

assay

99%

bp

115-120 °C/0.5 mmHg (lit.)

mp

105-107 °C (dec.) (lit.)

functional group

ketone

SMILES string

COc1cccc2C(=O)CCc12

InChI

1S/C10H10O2/c1-12-10-4-2-3-7-8(10)5-6-9(7)11/h2-4H,5-6H2,1H3

InChI key

BTYSYELHQDGJAB-UHFFFAOYSA-N

说明

General description

4-Methoxy-1-indanone, a benzo-fused ketone is a 1-indanone derivative. Its synthesis has been reported.

Application

4-Methoxy-1-indanone is suitable for use in the comparative study of the effect of different substituents on various benzo-fused ketones on the reaction kinetics by studying the biocatalysed oxidation reaction.
It may be used in the following studies:

Synthesis of isomeric mixture of oximes.
As a starting material in the synthesis of benzo-fused indolizidine and 4-methoxy-1-indanyl compound.
Synthesis of 4-methoxy-5-nitro-1-indanone by nitration reaction.
As one of the reactant in the synthesis of E-2-chloro-8-methyl-3-[(4′-methoxy-1′-indanoyl)-2′-methyliden]-quinoline (IQ), a quinoline derivative.

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

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Synthesis of benzo-fused 1-azabicyclo[m.n.0]alkanes via the Schmidt reaction: a formal synthesis of gephyrotoxin.

W H Pearson et al.

The Journal of organic chemistry, 65(21), 7158-7174 (2000-10-14)

The intramolecular capture of benzocyclobutyl, benzocyclopentyl, and benzocyclohexyl carbocations 7 by azides produces spirocyclic aminodiazonium ions 8, which undergo 1,2-C-to-N rearrangement with loss of dinitrogen to produce benzo-fused iminium ions resulting from either aryl (9) or alkyl (10) migration to

Enzymatic Baeyer-Villiger Oxidation of Benzo-Fused Ketones: Formation of Regiocomplementary Lactones.

Rioz-Martinez A, et al.

European Journal of Organic Chemistry, 2009(15), 2526-2532 (2009)

Beckmann rearrangements of 1-indanone oxime derivatives using aluminum chloride and mechanistic considerations.

Lee BS, et al.

Bull. Korean Chem. Soc., 21(9), 860-866 (2000)

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全球贸易项目编号

货号	GTIN
392529-1G	04061831981551