39410
聚合物键合型 4-(二甲氨基)吡啶
extent of labeling: ~3.0 mmol/g "DMAP" loading, matrix crosslinked with 2% DVB
别名:
4-(Dimethylamino)pyridine on Polystyrene, DMAP on PS, polymer bound DMAP
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关于此项目
经验公式（希尔记法）:
C8H8
化学文摘社编号:
分子量:
104.15
UNSPSC Code:
12352128
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
聚合物键合型 4-(二甲氨基)吡啶, extent of labeling: ~3.0 mmol/g "DMAP" loading, matrix crosslinked with 2% DVB
reaction suitability
reaction type: solution phase peptide synthesis
extent of labeling
~3.0 mmol/g "DMAP" loading
matrix
crosslinked with 2% DVB
anion traces
chloride (Cl-): ≤5000 mg/kg
Quality Level
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Application
聚合物结合的4-（二甲氨基）吡啶在Michael加成和亚硝酸消除工艺步骤中用作负载碱，该步骤涉及在通用和基于方案的有效连续流动下使用β-硝基丙烯酸酯作为起始物料合成噻吩-2-羧酸酯。在固体非均相催化下，它还可以作为负载型催化剂，以环状2-硝基酮为起始原料制备ω-硝基酯。（5）
General description
聚合物结合的4-（二甲氨基）吡啶用于改善手性和非手性脂族胺、氨基醇和氨基酸的衍生化。
Other Notes
聚合物负载的可回收酰化催化剂
聚合物负载的可回收酰化催化剂
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
A new, low impact and efficient synthesis of $\omega$-nitro esters under solid heterogeneous catalysis
Chiurchiu E, et al.
Green Chemistry, 19(20), 4956-4960 (2017)
$\beta$-Nitroacrylates as Starting Materials of Thiophene-2-Carboxylates Under Continuous Flow Conditions
Chiurchiu E, et al.
Advanced Synthesis & Catalysis, 361(9), 2042-2047 (2019)
$\beta$-Nitroacrylates as Starting Materials of Thiophene-2-Carboxylates Under Continuous Flow Conditions
Chiurchiu E, et al.
advanced synthesis and catalysis, 361(9), 2042-2047 (2019)
M. Tomoi et al.
Macromol. Chem. Rapid Commun., 3, 537-537 (1982)
Szu-Yuan Chou et al.
Scientific reports, 10(1), 18519-18519 (2020-10-30)
Cell development and behavior are driven by internal genetic programming, but the external microenvironment is increasingly recognized as a significant factor in cell differentiation, migration, and in the case of cancer, metastatic progression. Yet it remains unclear how the microenvironment
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