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Merck
CN

394408

1-(溴乙酰)芘

97%

别名:

2-Bromo-1-(1-pyrenyl)ethanone

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关于此项目

经验公式(希尔记法):
C18H11BrO
化学文摘社编号:
分子量:
323.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
solid
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Quality Segment

assay

97%

form

solid

mp

129-131 °C (lit.)

functional group

bromo, ketone

SMILES string

BrCC(=O)c1ccc2ccc3cccc4ccc1c2c34

InChI

1S/C18H11BrO/c19-10-16(20)14-8-6-13-5-4-11-2-1-3-12-7-9-15(14)18(13)17(11)12/h1-9H,10H2

InChI key

KAEDEGFCOPIKKM-UHFFFAOYSA-N

General description

1-(Bromoacetyl)pyrene (BAP) is a pyrene derivative. It has been synthesized by reacting cupric bromide with 1-acetylpyrene. Studies suggest that the introduction of a bromoacetyl chromophoric moiety to pyrene drastically increases the photoinitiating efficiency of pyrenes.

Application

1-(Bromoacetyl)pyrene is suitable for use in the following studies:
  • As an initiator in the bulk polymerization of 2-ethyl-2-oxazoline to generate pyrene labelled poly(2-ethyl-2-oxazoline) (PETOX-py).
  • As a fluorophore in the generation of podand-type fluoroionophores with two pyrene moieties.
  • As a fluorescent labeling agent for the determination of okadaic acid toxin by HPLC with fluorescence detection.
It may also be used in the following studies:
  • As a photoremovable protecting group for carboxylic acids and amino acids.
  • As a photoinitiator in the photopolymerization of styrene with methylmethacrylate.
  • As a reactant in the synthesis of potentially tetradentate pyrene appended ligands.
  • As a derivatizing agent of dialkyl phosphates (DAP) in the HPTLC method of quantitative determination of DAP in fruit juices.


象形图

Corrosion

警示词

Danger

危险代码

Hazard Classifications

Aquatic Chronic 4 - Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

怎么回事?

WGK 3

闪点 (F)

Not applicable

闪点 (°C)

Not applicable

PPE(个人防护设备)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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