1-(溴乙酰)芘

Name: 1-(溴乙酰)芘
Brand: ALDRICH

97%

别名:

2-Bromo-1-(1-pyrenyl)ethanone

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About This Item

经验公式（希尔记法）:

C₁₈H₁₁BrO

CAS Number:

80480-15-5

分子量:

323.18

MDL编号:

MFCD00191839

UNSPSC代码:

12352100

PubChem化学物质编号:

24864593

NACRES:

NA.22

质量水平

100

方案

97%

表单

solid

mp

129-131 °C (lit.)

官能团

bromo
ketone

SMILES字符串

BrCC(=O)c1ccc2ccc3cccc4ccc1c2c34

InChI

1S/C18H11BrO/c19-10-16(20)14-8-6-13-5-4-11-2-1-3-12-7-9-15(14)18(13)17(11)12/h1-9H,10H2

InChI key

KAEDEGFCOPIKKM-UHFFFAOYSA-N

一般描述

1-(Bromoacetyl)pyrene (BAP) is a pyrene derivative. It has been synthesized by reacting cupric bromide with 1-acetylpyrene. Studies suggest that the introduction of a bromoacetyl chromophoric moiety to pyrene drastically increases the photoinitiating efficiency of pyrenes.

应用

1-(Bromoacetyl)pyrene is suitable for use in the following studies:

As an initiator in the bulk polymerization of 2-ethyl-2-oxazoline to generate pyrene labelled poly(2-ethyl-2-oxazoline) (PETOX-py).
As a fluorophore in the generation of podand-type fluoroionophores with two pyrene moieties.
As a fluorescent labeling agent for the determination of okadaic acid toxin by HPLC with fluorescence detection.

It may also be used in the following studies:

As a photoremovable protecting group for carboxylic acids and amino acids.
As a photoinitiator in the photopolymerization of styrene with methylmethacrylate.
As a reactant in the synthesis of potentially tetradentate pyrene appended ligands.
As a derivatizing agent of dialkyl phosphates (DAP) in the HPTLC method of quantitative determination of DAP in fruit juices.