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Merck
CN

398845

醋酸铅(IV)

≥99.99% trace metals basis

别名:

Pb(acac)4, 四乙酸铅

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关于此项目

线性分子式:
Pb(CH3CO2)4
化学文摘社编号:
分子量:
443.38
EC Number:
208-908-0
UNSPSC Code:
12352300
PubChem Substance ID:
Beilstein/REAXYS Number:
3595640
MDL number:
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assay

≥99.99% trace metals basis

reaction suitability

core: lead, reagent type: catalyst

SMILES string

CC(=O)O[Pb](OC(C)=O)(OC(C)=O)OC(C)=O

InChI

1S/4C2H4O2.Pb/c4*1-2(3)4;/h4*1H3,(H,3,4);/q;;;;+4/p-4

InChI key

JEHCHYAKAXDFKV-UHFFFAOYSA-J

Application

平稳地诱导向烯烃和炔烃中添加二氟二碘甲烷。


signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1A - STOT RE 2

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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历史批次信息供参考:

分析证书(COA)

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Li, A-R. Chen, Q-Y.
Synthesis, 1481-1481 (1997)
Luis Moreno-Osorio et al.
Magnetic resonance in chemistry : MRC, 45(11), 993-996 (2007-09-19)
Two naturally occurring 11-nordrimanes were synthesized, and their (1)H and (13)C NMR spectra were unambiguously assigned in full for the first time.
Hidehito Urata et al.
Chemical & pharmaceutical bulletin, 56(11), 1611-1612 (2008-11-05)
The first chemical synthesis of two metabolites ((1R,2S,5R,6S)-6-(3,4-dihydroxyphenyl)-2-(3,4-methylenedioxyphenyl)-3,7-dioxabicyclo[3,3,0]octane (SC-1) and (1R,2S,5R,6S)-2,6-bis(3,4-dihydroxyphenyl)-3,7-dioxabicyclo[3,3,0]octane (SC-2)) of sesamin was achieved by a simple two-step approach from sesamin. The approach consists of acetoxylation of the methylenedioxy moiety(ies) with lead(IV) tetraacetate and acid hydrolysis of the