399116
三碘化镓
99.99% trace metals basis
别名:
Gallium triiodide, Triiodogallane
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关于此项目
线性分子式:
GaI3
化学文摘社编号:
分子量:
450.44
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
236-611-6
MDL number:
Assay:
99.99% trace metals basis
Form:
powder and chunks
assay
99.99% trace metals basis
form
powder and chunks
reaction suitability
core: gallium, reagent type: catalyst
impurities
≤150.0 ppm Trace Metal Analysis
mp
345 °C (subl.) (lit.)
density
4.15 g/mL at 25 °C (lit.)
SMILES string
I[Ga](I)I
InChI
1S/Ga.3HI/h;3*1H/q+3;;;/p-3
InChI key
DWRNSCDYNYYYHT-UHFFFAOYSA-K
General description
三碘化镓是固体无机物，高熔点、低挥发性。在各领域应用广泛。用于半导体、氮化镓晶体的生产。用于有机合成。
Application
三碘化镓可用于：
- 作为比吉内利反应催化剂，合成二氢嘧啶-2(1H)-酮衍生物。
- 作为(Z)-β-碘Baylis–Hillman加合物立体选择性合成反应和aza-Prins环化反应的试剂。
- 作为前体合成高结晶度氮化镓晶体用于能量转换装置。
- 作为起始材料合成高纯度硫系玻璃。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Repr. 2 - Skin Corr. 1B - Skin Sens. 1
存储类别
8B - Non-combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Gallium (III) Iodide-catalyzed Biginelli-type Reaction Under Solvent-free Conditions: Efficient Synthesis of Dihydropyrimidine-2 (1H)-one Derivatives
Dapeng Li, et al.
Chin. J. Chem., 28, 2025-2032 (2010)
Gallium iodide/iodine as a versatile reagent for the aza-Prins cyclization: an expeditious synthesis of 4-iodopiperidines
J.S. Yadav, et al
Tetrahedron Letters, 49, 3330-3334 (2008)
Rapid synthesis of crystalline gallium nitride from solid precursors at atmospheric pressure
Charles H Wallace, et al.
Chemistry of Materials, 11, 2299-2301 (1999)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 399116-10G | 04061833597408 |