399205
反,反-氯化法呢酯
97%
别名:
反,反-1-氯-3,7,11-三甲基-2,6,10-十二碳三烯
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关于此项目
线性分子式:
(CH3)2C=CH[CH2CH2C(CH3)=CH]2CH2Cl
化学文摘社编号:
分子量:
240.81
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
liquid
InChI
1S/C15H25Cl/c1-13(2)7-5-8-14(3)9-6-10-15(4)11-12-16/h7,9,11H,5-6,8,10,12H2,1-4H3/b14-9+,15-11+
SMILES string
[H]\C(CCl)=C(\C)CC\C([H])=C(/C)CC\C([H])=C(/C)C
InChI key
BJVUJIDTICYHLL-YFVJMOTDSA-N
assay
97%
form
liquid
refractive index
n20/D 1.493 (lit.)
bp
59-60 °C/2.4 mmHg (lit.)
density
0.916 g/mL at 25 °C (lit.)
functional group
alkyl halide, chloro
storage temp.
2-8°C
Quality Level
General description
Physical properties (density, refractive index and boiling point) of trans,trans-farnesyl chloride have been reported.
Application
trans,trans-Farnesyl chloride (all-trans-farnesyl chloride) is suitable for use in the preparation of (S)-farnesyl thiopyrophosphate.
Farnesyl chloride may be used in the synthesis of isoprenoid conjugates of nucleoside 5′-diphosphates.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
Youngha Ryu et al.
Organic letters, 5(24), 4713-4715 (2003-11-25)
[reaction: see text] Isoprenoid conjugates of nucleoside 5'-diphosphates were efficiently synthesized by one-step nucleophilic displacement reactions of either isoprenyl chlorides or isopentenyl tosylate with nucleoside 5'-diphosphates.
Yaws CL.
The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals, 487-487 (2015)
Yi-Hung Chen et al.
The Journal of biological chemistry, 277(9), 7369-7376 (2001-12-18)
Undecaprenyl pyrophosphate synthase (UPPS) catalyzes the consecutive condensation reactions of eight isopentenyl pyrophosphate (IPP) with farnesyl pyrophosphate (FPP) to generate C(55) undecaprenyl pyrophosphate (UPP). In the present study, site-directed mutagenesis, fluorescence quenching, and stopped-flow methods were utilized to examine the
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