产品名称
反-4-甲氧基-β-硝基苯乙烯, 99%
InChI
1S/C9H9NO3/c1-13-9-4-2-8(3-5-9)6-7-10(11)12/h2-7H,1H3/b7-6+
SMILES string
[H]\C(=C(\[H])[N+]([O-])=O)c1ccc(OC)cc1
InChI key
JKQUXSHVQGBODD-VOTSOKGWSA-N
assay
99%
mp
86-88 °C (lit.)
solubility
chloroform: soluble 25 mg/mL, clear, yellow
functional group
amine
nitro
Quality Level
Application
trans-4-Methoxy-β-nitrostyrene acts as guest molecule and forms guest molecules forming co-crystal phases with the d-form of robust syndiotactic polystyrene (sPS). It may be employed as a Michael acceptor in the synthesis of proline based chiral ionic liquid catalysts with two five-membered unsaturated aza-heterocycles.
General description
trans-4-Methoxy-β-nitrostyrene participates in the Michael reaction on carbapenam intermediate.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
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Polymer co-crystalline films for photonics.
Daniel C, et al.
Journal of the European Optical Society: Rapid Publications, 4 (2009)
Proline Based Chiral Ionic Liquids for Enantioselective Michael Reaction.
Nobuoka K, et al.
Organic Chemistry International (2014)
Sachin A Pawar et al.
Organic & biomolecular chemistry, 11(48), 8294-8297 (2013-11-13)
Herein, we report the development of mild, organocatalyzed routes to novel carbapenam derivatives through aldol, Mannich and Michael C-C bond forming reactions.
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