39933
(S)-4-异丙基噻唑烷-2-硫酮
≥98.0%
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关于此项目
经验公式（希尔记法）:
C6H11NS2
化学文摘社编号:
分子量:
161.29
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
assay
≥98.0%
form
solid
optical activity
[α]20/D -37±3°, c = 1 in chloroform
optical purity
ee: ≥99:1 (LC)
mp
69-71 °C
SMILES string
CC(C)[C@H]1CSC(=S)N1
InChI
1S/C6H11NS2/c1-4(2)5-3-9-6(8)7-5/h4-5H,3H2,1-2H3,(H,7,8)/t5-/m1/s1
InChI key
CWIZUGZKLJDJLE-RXMQYKEDSA-N
Application
具有高度选择性和有效性的手性助剂，与二异丁基氢化铝发生还原裂解反应可直接还原为相应的醛和手性助剂。
(S)-4-Isopropylthiazolidine-2-thione may be used as a chiral auxiliary for the stereochemical induction at the phosphorus atom during the diastereoselective synthesis of aryloxy phosphoramidate prodrugs of 3′-deoxy-2′,3′-didehydrothymidine monophosphate (d4TMP).
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)