400068
四氟硼酸-二乙醚络合物
别名:
氟硼酸-二乙醚络合物
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关于此项目
线性分子式:
HBF4 · O(CH2CH3)2
化学文摘社编号:
分子量:
161.93
UNSPSC Code:
12352301
PubChem Substance ID:
NACRES:
NA.22
EC Number:
267-983-8
MDL number:
Assay:
51-57%
Form:
liquid
SMILES string
[F.FB(F)F.CCOCC], F.FB(F)F.CCOCC
InChI key
[XFHGDBFMJCLEOW-UHFFFAOYSA-N], XFHGDBFMJCLEOW-UHFFFAOYSA-N
InChI
[1S/C4H10O.BF3.FH/c1-3-5-4-2;2-1(3)4;/h3-4H2,1-2H3;;1H], 1S/C4H10O.BF3.FH/c1-3-5-4-2;2-1(3)4;/h3-4H2,1-2H3;;1H
assay
51-57%
form
liquid
density
1.19 g/mL at 20 °C (lit.), 1.18 g/mL at 25 °C
functional group
ether
storage temp.
2-8°C
Quality Level
Application
四氟硼酸二乙醚络合物可用于促进膦硼烷从双膦硼烷络合物分解，以制备双膦配体。它也可以作为配体与过渡金属配合物合成。
signalword
Danger
hcodes
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 1
flash_point_f
264.2 °F - closed cup
flash_point_c
129 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - Water-react. 2
Dynamic behavior of dicobalt hexacarbonyl propargyl cations and their reactions with chiral nucleophiles.
Schreiber S, et al.
Journal of the American Chemical Society, 109(19), 5749-5759 (1987)
Chelated ? 5-cyclopentadienyl-?-ethyl complexes of molybdenum and tungsten; molecular structure of W (? 5-C 5 H 4 CH 2-?-CH 2)(CO) 3.
Amor F, et al.
Journal of Organometallic Chemistry, 604(1), 126-131 (2000)
An efficient procedure for the synthesis of C-chiral bisphosphines.
McKinstry L, et al.
Tetrahedron, 51(28), 7655-7666 (1995)
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